Journal of Industrial and Engineering Chemistry, Vol.84, 340-348, April, 2020
Fabricated superhydrophobic three-dimensional rambutan-like-β-NiOOH @sponge skeletons for multitasking oil?water separation
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In this paper, oleophilic and superhydrophobic sponges were successfully constructed via a one-pot low temperature hydrothermal method anchoring three-dimensional rambutan-like-β-NiOOH microspheres into sponge skeletons and lauric acid modification. The constructed modified three-dimensional rambutan-like-β-NiOOH @sponge (the static contact angle of 153.5°) possessed outstanding oil sorption capacity (separation efficiency is nearly 99%) towards the various organics/oils and excellent recyclability after 30 cycles of adsorption-squeezing. Importantly, modified three-dimensional rambutan-like-β-NiOOH @sponge is capable of separating surfactant-stabilized water-in-oil emulsions and can be utilized for continuous oil-water separation with the aid of a peristaltic pump. This is mainly due to the fact that the three-dimensional hierarchical rambutan-like micronano structure formed by self-assembly with high specific surface area provides a large number of hydrophobic interfaces to improve the hydrophobic properties of sponges. This work presents a new strategy for the designs multitasking oil-water separation materials.
Keywords:3D rambutan-like-β-NiOOH;Emulsion separation;Non-fluorinated;One-pot low temperature hydrothermal method;Superhydrophobic sponge
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