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Journal of Industrial and Engineering Chemistry, Vol.84, 393-399, April, 2020
Ecklonia cava based mesoporous activated carbon for high-rate energy storage devices
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Activated carbon has received enormous global attention as an electrode material for electrical double layer capacitors (EDLCs) due to its superior electrochemical performance. But while manufacturing high-quality activated carbon as an electrode material, overcoming limitations such as depletion of raw material resources, poor high-rate performance, and cycle stability is still a significant challenge. To address these limitations, we firstly suggest a novel mesoporous activated carbon derived from ecklonia cava (Meso-ACDE) using an acid-base reaction and KOH activation processes. The optimized Meso-ACDE electrode showed a superior specific capacitance of 182 F g-1 at the current density of 0.2 A g-1 and a high-rate capacitance of 154 F g-1 at the current density of 20.0 A g-1 with an excellent cycling stability up to 2000 cycles. The enhanced electrochemical performance of the Meso-ACDE electrode was mainly attributed to the well-developed mesoporous structure with a high concentration of oxygen related functional groups, which were acquired during the activation process. Thus, we believe that the Meso-ACDE could be a promising alternative to conventional activated carbon for high-performance EDLCs.
Keywords:Electrical double-layer capacitors;Activated carbon;Ecklonia cava;Mesoporous structure;Rate performance
- Raza W, Ali F, Raza N, Luo Y, Kim KH, Yang J, Kumar S, Mehmood A, Kwon E, Nano Energy, 52, 441 (2018)
- Faraji S, Ani FN, Renew. Sust. Energ. Rev., 42, 823 (2015)
- Sun F, Gao JH, Liu X, Pi XX, Yang YQ, Wu SH, Appl. Surf. Sci., 387, 857 (2016)
- Inagaki M, Konno H, Tanaike O, Carbon, 195, 7880 (2010)
- Inal IIG, Holmes SM, Yagmur E, Ermumcu N, Banford A, Aktas Z, J. Ind. Eng. Chem., 61, 124 (2018)
- Awasthi GP, Bhattarai DP, Maharjan B, Kim KS, Park CH, Kim CS, J. Ind. Eng. Chem., 72, 265 (2019)
- Simon P, Gogotsi Y, Dunn B, Science, 343(6176), 1210 (2014)
- Simon P, Gogotsi Y, Nat. Mater., 7(11), 845 (2008)
- Miller JR, Appl. Surf. Sci., 460, 3 (2018)
- An GH, Koo BR, Ahn HJ, Phys. Chem. Chem. Phys., 18, 6587 (2016)
- An GH, Lee DY, Ahn HJ, J. Mater. Chem. A, 5, 19714 (2017)
- An H, Wang Y, Wang X, Li N, Zheng L, J. Solid State Electrochem., 14, 651 (2010)
- Inal IIG, Holmes SM, Banford A, Aktas Z, Appl. Surf. Sci., 357, 696 (2015)
- Mo RJ, Zhao Y, Wu M, Xiao HM, Kuga S, Huang Y, Li JP, Fu SY, RSC Adv., 6, 59333 (2016)
- Wang H, Xu Z, Kohandehghan A, Li Z, Cui K, Tan X, Stephenson TJ, King’ondu CK, Holt CMB, Olsen BC, Tak JK, Harfield D, Anyia AO, Mitlin D, ACS Nano, 7, 5131 (2013)
- Wang YY, Hou BH, Lu HY, Lu CL, Wu XL, ChemistrySelect, 1, 1441 (2016)
- Rufford TE, Hulicova-Jurcakova D, Zhu Z, Lu GQ, Electrochem. Commun., 10, 1594 (2008)
- Wu FC, Tseng RL, Hu CC, Wang CC, J. Power Sources, 138(1-2), 351 (2004)
- Balathanigaimani MS, Shim WG, Lee MJ, Kim C, Lee JW, Moon H, Electrochem. Commun., 10, 868 (2008)
- Kishore B, Shanmughasundaram D, Penki TR, Munichandraiah N, J. Appl. Electrochem., 44(8), 903 (2014)
- Redondo E, Carretero-Gonzalez J, Goikolea E, Segalini J, Mysyk R, Electrochim. Acta, 160, 178 (2015)
- Raymundo-Pinero E, Cadek M, Beguin F, Adv. Funct. Mater., 19(7), 1032 (2009)
- An GH, Lee DY, Ahn HJ, J. Ind. Eng. Chem., 65, 423 (2018)
- Yu W, Wang H, Liu S, Mao N, Liu X, Shi J, Lui W, Chen S, Wang X, J. Mater. Chem. A, 4, 5973 (2016)
- Keishnan V, Sasikumar S, Dass FP, Vijayaraghavan R, Trends Biomater. Artif. Organs., 24, 139 (2010)
- Zhang H, Mo Z, Guo R, Liu N, Yan M, Wang R, Feng H, Wei X, J. Mater. Res., 15, 1200 (2019)
- Otowa T, Tanibata R, Itoh M, Gas Sep. Purif., 7, 241 (1993)
- An GH, Ahn HJ, J. Power Sources, 272, 828 (2014)
- An GH, Lee EH, Ahn HJ, J. Alloy. Compd., 682, 746 (2016)
- Lee DY, Ah GH, Ahn HJ, J. Ind. Eng. Chem., 52, 121 (2017)
- Chen H, Wang G, Chen L, Dai B, Yu F, Nanomaterials, 8, 412 (2018)
- An GH, Ahn HJ, J. Electroanal. Chem., 744, 32 (2015)
- Raymundo-Pinero E, Leroux F, Beguin F, Adv. Mater., 18(14), 1877 (2006)
- Largeot C, Portet C, Chmiola J, Taberna PL, Gogotsi Y, Simon P, J. Am. Chem. Soc., 130(9), 2730 (2008)
- Sun H, He W, Zong C, Lu L, ACS Appl. Mater. Interfaces, 5, 2261 (2013)
- Biswal M, Banerjee A, Deo M, Ogale S, Energy Environ., 6, 1249 (2013)
- Long C, Chen X, Jiang L, Zhi L, Fan Z, Nano Energy, 12, 141 (2015)
- An GH, Ahn HJ, Hong WK, J. Power Sources, 274, 536 (2015)
- Lang JW, Yan XB, Liu WW, Wang RT, Xue QJ, J. Power Sources, 204, 220 (2012)
- Yang X, Zhang L, Zhang F, Zhang T, Huang Y, Chen Y, Carbon, 72, 381 (2014)
- An GH, Sohn JI, Ahn HJ, J. Mater, Chem. A, 4, 2049 (2016)