Alkali 방법을 이용한 Block Silicone Softener 합성 및 응용

Kun Chen; Xiangdong Zhou

Polymer(Korea), Vol.44, No.2, 146-153, March, 2020

DOI10.7317/pk.2020.44.2.146 Export Citation

Alkali 방법을 이용한 Block Silicone Softener 합성 및 응용

Synthesis of a Block Silicone Softener by Alkali Method and Its Application on Cotton Fabric

Kun Chen, and Xiangdong Zhou^{1, †}

Hangzhou Meigao Huayi Chemical Co., Ltd., Hangzhou 311231, China
¹College of Textile and Clothing Engineering, National Engineering Laboratory for Modern Silk, Soochow University, Suzhou 215021, China

E-mail:

A block silicone softener (ATSO-PDE) was synthesized by alkali method with amino-terminated polysiloxane (ATSO) and polypropylene glycol diglycidyl ether (PDE) as raw materials. The chemical structure of amino-terminated siloxane (ATS) was characterized by 1H NMR, 13C NMR, and FTIR. The main factors affecting ATSO conversion rate and properties of product were investigated. The optimal ring opening reaction condition of ATSO was 110℃ for 2 h. The application of ATSO-PDE on cotton fabrics indicated that fabrics treated by softener with high ammonia value (0.70 mmol/g) expressed good softness while softener with low ammonia value (0.40 mmol/g) expressed good smoothness. The adsorption mechanism and orientation distribution of silicone softener on the fibers were analyzed by the establishment of the orientation distribution model. It was indicated that the different properties and surface morphology of ATSO-PDE were related to the molecular structure and the orientation on the surface of the fiber.

Keywords:alkali method;softener;block silicone;film morphology;orientation

[References]

An Q, Zhao J, Li X, J. Appl. Polym. Sci., 16, 40612 (2014)
Nguyen L, Hang M, Wang WX, Tian Y, Wang LM, Thomas J, McCarthy, Chen W, ACS Appl. Mater. Inter., 24, 22876 (2014)
Yuan W, Cheng Z, Peng C, Polym. Bull., 76, 447 (2018)
Xu Y, Yin H, Yuan S, Appl. Surf. Sci., 20, 8435 (2009)
Li M, An Q, Huang L, Surf. Interface Anal., 5, 914 (2008)
Hou A, Shi Y, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 2, 99 (2009)
Xie K, Chen Y, Hou A, J. Dispersion Sci. Technol., 10, 1474 (2009)
Zuber M, Zia KM, Tabassum S, Int. J. Biol. Macromol., 1, 1 (2011)
Zia KM, Tabassuma S, Hasina SB, Zubera M, Mu TJ, Int. J. Biol. Macromol., 3, 482 (2011)
Kang TJ, Kim MS, Text. Res. J., 4, 295 (2001)
Gutierrez MC, Lopez-Mesas M, Lacorte MT, Fiber. Polym., 10, 437 (2009)
Xu YJ, Yin H, Zheng HF, Yuan SF, Chen ZR, J. Appl. Polym. Sci., 119(4), 2326 (2011)
Jin Y, Pu Q, Fan H, ACS Appl. Mater. Inter., 14, 7552 (2015)
Burrell MC, Butts MD, Derr D, Genovese S, Perry RJ, Appl. Surf. Sci., 227(1-4), 1 (2004)

[1] An Q, Zhao J, Li X, J. Appl. Polym. Sci., 16, 40612 (2014)

[2] Nguyen L, Hang M, Wang WX, Tian Y, Wang LM, Thomas J, McCarthy, Chen W, ACS Appl. Mater. Inter., 24, 22876 (2014)

[3] Yuan W, Cheng Z, Peng C, Polym. Bull., 76, 447 (2018)

[4] Xu Y, Yin H, Yuan S, Appl. Surf. Sci., 20, 8435 (2009)

[5] Li M, An Q, Huang L, Surf. Interface Anal., 5, 914 (2008)

[6] Hou A, Shi Y, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 2, 99 (2009)

[7] Xie K, Chen Y, Hou A, J. Dispersion Sci. Technol., 10, 1474 (2009)

[8] Zuber M, Zia KM, Tabassum S, Int. J. Biol. Macromol., 1, 1 (2011)

[9] Zia KM, Tabassuma S, Hasina SB, Zubera M, Mu TJ, Int. J. Biol. Macromol., 3, 482 (2011)

[10] Kang TJ, Kim MS, Text. Res. J., 4, 295 (2001)

[11] Gutierrez MC, Lopez-Mesas M, Lacorte MT, Fiber. Polym., 10, 437 (2009)

[12] Xu YJ, Yin H, Zheng HF, Yuan SF, Chen ZR, J. Appl. Polym. Sci., 119(4), 2326 (2011)

[13] Jin Y, Pu Q, Fan H, ACS Appl. Mater. Inter., 14, 7552 (2015)

[14] Burrell MC, Butts MD, Derr D, Genovese S, Perry RJ, Appl. Surf. Sci., 227(1-4), 1 (2004)