Synthesis of Highly Durable Sulfonated Polyketone Fibers by Direct Sulfonation Reaction and Their Adsorption Properties for Heavy Metals

Seong Yeon Hwang; Yong Seok Cho; Taekeun Kim; Yoon Seo Jung; Taek Sung Hwang

Macromolecular Research, Vol.28, No.4, 336-342, April, 2020

DOI10.1007/s13233-020-8046-8 Export Citation

Synthesis of Highly Durable Sulfonated Polyketone Fibers by Direct Sulfonation Reaction and Their Adsorption Properties for Heavy Metals

Seong Yeon Hwang, Yong Seok Cho, Taekeun Kim¹, Yoon Seo Jung, and Taek Sung Hwang^†

Department of Applied Chemical Engineering, College of Engineering, Chungnam National University, 99 Daehak-ro, Yuseoung-gu, Daejeon 34134, Korea
¹Department of Chemical Engineering Education, College of Education, Chungnam National University, 99 Daehak-ro, Yuseoung-gu, Daejeon 34134, Korea

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In this study, sulfonated polyketone (SPK) cation exchange fibers were prepared by direct sulfonation with various concentration of sulfonating agent and sulfonation time. Fourier-transform infrared (FTIR) spectrum analysis was performed to confirm the structure of the sulfonated polyketone cation exchange fibers. The degree of sulfonation (DOS) and water uptake (W.U) of SPK cation exchange fibers were measured by gravimetric method and ion exchange capacity (IEC) was measured by titration method, respectively. The DOS of the SPK cation exchange fibers increased with sulfonation time and concentration of sulfonating agent. The SPK cation exchange fibers sulfonated for 15 min at a mole ratio of 1:2 of polyketone to chlorosulfonic acid had the DOS of 47%, ion exchange capacity 3.36 meq/g, and water content 35.1%, showing the best performance.

Keywords:Ion exchange fiber;chlorosulfonic acid;degree of sulfonation and heavy metal ions

[References]

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Park JS, Nho YC, Polym. Korea, 22(1), 47 (1998)
Lufrano F, Gatto I, Staiti P, Antonucci V, Passalacqua E, Solid State Ion., 145(1-4), 47 (2001)
Yan G, Viraraghavan T, Water Res., 37, 4486 (2003)
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Yoshioka T, Bull. Chem. Soc. Japan, 58, 2618 (1985)
Lee JW, Kim SH, Hwang GS, J. Korea Academia-Industrial, 18, 584 (2017)

[1] Wei JF, Wang ZP, Zhang J, Wu YY, Zhang ZP, Xiong CH, React. Funct. Polym., 65(1-2), 127 (2005)

[2] Kampalanonwat P, Supaphol P, ACS Appl. Mater. Inter.,, 2, 3619 (2010)

[3] Rix FC, Brookhart M, White PS, J. Am. Chem. Soc., 118(20), 4746 (1996)

[4] Bianchini C, Meli A, Coord. Chem. Rev., 225, 35 (2002)

[5] Belov GP, Novikova EV, Russian Chem. Rev., 73, 267 (2004)

[6] Sommazzi A, Garbassi F, Prog. Polym. Sci, 22, 1547 (1997)

[7] Ataollahi N, Vezzu K, Nawn G, Pace G, Cavinato G, Girardi F, Scardi P, Di Noto V, Di Maggio R, Electrochim. Acta, 226, 148 (2017)

[8] Kim IS, Hwang CW, Kim YJ, Canlier A, Jeong KS, Hwang TS, Macromol. Res., 25(11), 1063 (2017)

[9] Paronen M, Sundholm F, Ostrovskii D, Jacobsson P, Jeschke G, Rauhala E, Tikkanen P, Chem. Mater., 15, 4447 (2003)

[10] Kang KW, Hwang TS, Membr. J., 25, 406 (2015)

[11] Wang F, Hickner M, Kim YS, Zawodzinski TA, McGrath JE, J. Membr. Sci., 197(1-2), 231 (2002)

[12] Ghassemi H, McGrath JE, Zawodzinski TA, Polymer, 47(11), 4132 (2006)

[13] Johnson BC, Yilgor I, Tran C, Iqbal M, Wightman JP, Lloyd DR, McGrath JE, J. Polym. Sci., Polym. Chem. Ed., 22, 721 (1984)

[14] Lin YF, Yen CY, Hung CH, Hsiao YH, Ma CCM, J. Power Sources, 168(1), 162 (2007)

[15] Reddy MV, Reddy GCS, Kalla RMN, Jeong YT, RSC Adv., 5, 35267 (2015)

[16] Staiti P, Lufrano F, Arico AS, Passalacqua E, Antonucci V, J. Membr. Sci., 188(1), 71 (2001)

[17] Li XF, Zhao CJ, Lu H, Wang Z, Na H, Polymer, 46(15), 5820 (2005)

[18] Kang KW, Hwang CW, Hwang TS, Macromol. Res., 23(12), 1126 (2015)

[19] Xu L, Lee HK, J. Chromatogr. A, 1216, 6549 (2009)

[20] Shin JP, Park JI, Lee SB, Seo DH, Kim JH, Membr. J., 14, 173 (2004)

[21] Kwak NS, Hwang TS, Kim SM, Yang YK, Kang KS, Polym. Korea, 28(5), 397 (2004)

[22] Park JS, Nho YC, Polym. Korea, 22(1), 47 (1998)

[23] Lufrano F, Gatto I, Staiti P, Antonucci V, Passalacqua E, Solid State Ion., 145(1-4), 47 (2001)

[24] Yan G, Viraraghavan T, Water Res., 37, 4486 (2003)

[25] Kim WY, Kim YS, Yug GC, Shin DY, Synthesis and Adsorption Properties for Heavy Metal Ions of Amidoxime Type Chelate Resin, 16, 277 (1992).

[26] Yoshioka T, Bull. Chem. Soc. Japan, 58, 2618 (1985)

[27] Lee JW, Kim SH, Hwang GS, J. Korea Academia-Industrial, 18, 584 (2017)