Synthesis of High Dimensionally Structured Mo-Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol

Shimoda K; Ishikawa S; Tashiro M; Kumaki M; Hiyoshi N; Ueda W

Inorganic Chemistry, Vol.59, No.8, 5252-5255, 2020

DOI10.1021/acs.inorgchem.9b03713 Export Citation

Synthesis of High Dimensionally Structured Mo-Fe Mixed Metal Oxide and Its Catalytic Activity for Selective Oxidation of Methanol

Shimoda K, Ishikawa S, Tashiro M, Kumaki M, Hiyoshi N, Ueda W

High-dimensionally structured Mo-Fe oxide (HDS-MoFeO) was synthesized through an assembly of structural units supplied from Keplerate-type polyoxometalate, {Mo72Fe30}, under an appropriate hydrothermal condition. HDS-MoFeO showed excellent catalytic activity for the selective oxidation of methanol with slightly lower selectivity for formaldehyde than that of a conventional Mo-Fe oxide catalyst.