Au-III-oxygen adducts have been implicated as intermediates in homogeneous and heterogeneous Au oxidation catalysis, but their reactivity is under-explored. Complex 1, ([Au-III(OH)-(terpy)](ClO4)(2), (terpy = 2,2':6',2-terpyridine), readily oxidized substrates bearing C-H and O-H bonds. Kinetic analysis revealed that the oxidation occurred through a hydrogen atom transfer (HAT) mechanism. Stable radicals were detected and quantified as products of almost quantitative HAT oxidation of alcohols by 1. Our findings highlight the possible role of Au-III-oxygen adducts in oxidation catalysis and the capability of late transition metal-oxygen adducts to perform proton coupled electron transfer.