International Journal of Hydrogen Energy, Vol.45, No.7, 4137-4151, 2020
Efficiency assessment of solar redox reforming in comparison to conventional reforming
Solar redox reforming is a process that uses solar radiation to drive the production of syngas from natural gas. This approach caught attention in recent years, because of substantially lower reduction temperatures compared to other redox cycles. However, a detailed and profound comparison to conventional solar reforming has yet to be performed. We investigate a two-step redox cycle with iron oxide and ceria as candidates for redox materials. Process simulations were performed to study both steam and dry methane reforming. Conventional solar reforming of methane without a redox cycle, i.e. on an established catalyst was used as reference. We found the highest efficiency of a redox cycle to be that of steam methane reforming with iron oxide. Here the solar-to-fuel efficiency is 43.5% at an oxidation temperature of 873 K, a reduction temperature of 1190 K, a pressure of 3 MPa and a solar heat flux of 1000 kW/m(2). In terms of efficiency, this process appears to be competitive with the reference process. In addition, production of high purity H-2 or CO is a benefit, which redox reforming has over the conventional approach. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.