화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.86, 113-122, June, 2020
DOI10.1016/j.jiec.2020.02.018  Export Citation
Application of synthesized bovine serum albumin-magnetic iron oxide for phosphate recovery
Muhammad Naveed Afridi, Won-Hee Lee, and Jong-Oh Kim†
  • Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea
E-mail:
Phosphorous is an essential nutrient that is widely used as a fertilizer in agriculture. However, its increased discharge from agricultural runoff contributes to eutrophication, necessitating its removal from wastewater. Adsorption is one of several treatment processes for this purpose. In this study, bovine serum albumin-magnetic iron oxide (BSA-MIO) was successfully synthesized using the co precipitation method. Its morphology was characterized by field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy. Different parameters that affect adsorption, such as initial phosphate concentration, reaction time, adsorbent dosage, pH, coexisting anions, and temperature, were investigated. The results showed that phosphate adsorption increased with reaction time and temperature while it decreased with an increase in solution pH. The phosphate adsorption equilibrium time using BSA-MIO was 1 h. The estimated maximum adsorption capacity of BSA-MIO was 20.7 mg Pㆍg-1. Moreover, the pseudo-second-order model (R2 > 0.99) and Langmuir model (R2 > 0.99) elucidated the better description of the adsorption kinetics and isotherm, respectively, thereby suggesting the chemisorption nature of adsorption. The coexisting anions (NO3 -, Cl-, SO4 2 -, and CO3 2 -) showed no significant effect on phosphate adsorption. Moreover, the adsorbed phosphate was successfully desorbed using different concentrations and combinations of NaOH and NaCl.
Keywords:Bovine serum albumin;Phosphate;Adsorption;Desorption;Wastewater;Reusability
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