화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.44, No.3, 325-333, May, 2020
DOI10.7317/pk.2020.44.3.325  Export Citation
천연검을 계면활성제로 사용한 자기치유 마이크로캡슐의 합성 및 물성
Synthesis and Properties of Self-healing Microcapsules
전효원1, 2, 정부영2, 천정미2, 황지원2, 이원기1, †, 천제환2, †
  • 1부경대학교 고분자공학과
  • 2한국신발피혁연구원
HyoWon Jun1, 2, Boo Young Jeong2, Jungmi Cheon2, JiWon Hwang2, Won-Ki Lee1, †, and Jae Hwan Chun2, †
  • 1Department of Polymer Engineering, Pukyoung National University, Busan 48547, Korea
  • 2Korea Institute of Footwear & Leather Technology, Busan 47154, Korea
E-mail:,
초록
본 연구에서 5종의 천연검을 계면활성제로 사용한 계면중합을 이용해 폴리우레탄 마이크로캡슐을 합성하였다. 실험에 사용된 천연검 수용액의 점도와 유화활성력을 측정하였으며, 합성된 마이크로캡슐은 free-NCO content 및 FTIR을 측정하고 광학현미경, FE-SEM, TGA로 분석하여 구형의 코어-쉘 구조를 확인하였다. 또한 마이크로캡슐을 열가소성 폴리우레탄에 적용하여 코팅제를 제조하고 손상을 주어 치유거동을 확인하였으며, 손상 전후와 치유 후의 물성을 측정하여 치유효율을 평가하였다. 천연검은 점도 및 오일방울의 크기에 대한 변수로 작용하여 캡슐의 형태를 변화시켰으며, 1.0 g 이하의 트라가칸스검을 사용하였을 때 가장 안정한 형태를 나타냈다.
In this study, microcapsules were synthesized by using five types of natural gums as surfactants. The viscosity and emulsifier activity (E24) of the natural gum solutions used in the experiment were measured, and synthesized microcapsules were confirmed by optical microscopy (OM), field emission scanning electron microscope (FE-SEM), Fourier transform infrared spectrometry (FTIR), thermogravimetric analyses (TGA) and free-NCO content to have a spherical core?shell structure. In addition, microcapsules were applied to thermoplastic polyurethane (TPU) to prepare and evaluate coatings to confirm healing behavior. Natural gums affected the synthesis of microcapsules, such as viscosity and oil droplet size. Stable microcapsules were synthesized using tragacanth gum (TG) in amounts diluted to 1.0 wt% or less in water.
Keywords:natural gum;self-healing;microcapsule;thermoplastic polyurethane coating
  1. Ahner J, Bode S, Micheel M, Dietzek B, Hager MD, Advances in Polymer Science Book Series, Springer, vol 273, 247 (2016)
  2. Garcia SJ, Eur. Polym. J., 53, 118 (2014)
  3. Yang JL, Keller MW, Moore JS, White SR, Sottos NR, Macromolecules, 41(24), 9650 (2008)
  4. Caruso MM, Blaiszik BJ, White SR, Sottos NR, Moore JS, Adv. Funct. Mater., 18(13), 1898 (2008)
  5. Yi H, Yang Y, Gu X, Huang J, Wang C, J. Mater. Chem. A, 3, 13749 (2015)
  6. Blaiszik BJ, Kramer SLB, Olugebefola SC, Moore JS, Sottos NR, White SR, Ann. Rev. Mater. Res., 40, 179 (2010)
  7. Williams KA, Dreyer DR, Bielawski CW, MRS Bulletin, 33, 759 (2008)
  8. Hager MD, Greil P, Leyens C, van der Zwaag S, Schubert US, Adv. Mater., 22(47), 5424 (2010)
  9. Caruso MM, Blaiszik BJ, Jin H, Schelkopf SR, Stradley DS, Sottos NR, Moore JS, ACS Appl. Mater. Interf, 2, 1195 (2010)
  10. Ullah H, Azizli KAM, Man ZB, Ismail MBC, Khan MI, Polym. Rev., 56, 429 (2016)
  11. Lee JK, Hong SJ, Liu X, Yoon SH, Macromol. Res., 12(5), 478 (2004)
  12. Cho SH, White SR, Braun PV, Adv. Mater., 21(6), 645 (2009)
  13. Moreno G, Valencia C, Franco JM, Gallegos C, Diogo A, Bordado JCM, Eur. Polym. J., 44, 2262 (2008)
  14. Kardar P, Progress Org. Coat., 89, 271 (2015)
  15. Han YC, Kim DH, Oh KS, Shin HJ, Yang JH, Jeong HM, Textile Color. Finish., 30, 90 (2018)
  16. Ma Y, Jiang Y, Tan H, Zhang Y, Gu J, Polymers, 9, 274 (2017)
  17. Zhu DY, Rong MZ, Zhang MQ, Prog. Polym. Sci, 49-50, 175 (2015)
  18. Song YK, Kim DM, Chung CM, Polym. Sci. Technol., 25(2), 121 (2014)
  19. Petrovic LB, Sovilj VJ, Katona JM, Milanovic JL, J. Colloid Interface Sci., 342(2), 333 (2010)
  20. Sharipova A, Aidarova S, Mutaliyeva B, Babayev A, Issakhov M, Issayeva A, Miller R, Colloids Interfaces, 1, 3 (2017)
  21. Garti N, Leser ME, Polym. Adv. Technol., 12, 123 (2001)
  22. Fan C, Zhou X, Polym. Bull., 67, 15 (2010)
  23. Lee J, Park S, Park CS, Kwon O, Chung S, Shim J, Bae J, Polymers, 10, 675 (2018)
  24. Ahmad S, Ahmad M, Manzoor K, Purwar R, Ikram S, Int. J. Biol. Macromol., 136, 870 (2019)
  25. de Villiers M, A Practical Guide to Contemporary Pharmacy Practice, Lippincott Williams and Wilkins, Philadelphia, p 251 (2009).
  26. Xiang W, Tardy B, Bai L, Stubenrauch C, Rojas OJ, Biobased Surfactants, Academic Press and AOCS Press, p 387 (2019).
  27. Dickinson E, Food Hydrocolloids, 17, 25 (2003)
  28. Kiyoyama S, Shiomori K, Kawano Y, Hatate Y, J. Microencapsul., 20(4), 497 (2003)
  29. Lim HK, Lee S, Mo DH, Lim JC, KICE, 50, 969 (2012)
  30. Zhuo L, Shuilin C, Inter. J. Polym. Mater., 53, 385 (2004)
  31. Huang M, Yang J, J. Mater. Chem., 21, 11123 (2011)
  32. Jyotsna KP, Dhirendra PS, Int. J. Innov. Sci. Res., 3, 88 (2014)
  33. Walter A, Rehage H, Leonhard H, Colloid Polym. Sci., 278, 169 (2000)
  34. Alizadegan F, Mirabedini SM, Pazokifard S, Moghadam SG, Farnood R, Prog. Org. Coat., 123, 350 (2018)
  35. Kardar P, Pigm. Resin Technol., 45, 73 (2016)
  36. Koh E, Kim NK, Shin J, Kim YW, RSC Adv., 4, 16214 (2014)
  37. Poljansek I, Fabjan E, Moderc D, Kukanja D, Int. J. Adhes. Adhes., 51, 87 (2014)
  38. Lapprand A, Boisson F, Delolme F, Mechin F, Pascault JP, Polym. Degrad. Stabil., 90, 363 (2005)
  39. Chung KH, Lee SH, Cho WS, Seo JY, Hong YK, J. Ind. Eng. Chem., 64, 284 (2018)
  40. Szmechtyk T, Sienkiewicz N, Strzelec K, Polym. Bull., 75, 149 (2017)
  41. Lim YJ, Song YK, Kim DM, Chung CM, Polym. Korea, 39(1), 56 (2015)
  42. Polydoropoulou P, Katsiropoulos C, Loukopoulos A, Pantelakis S, Int. J. Struct. Integr., 9, 753 (2018)