화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.37, No.6, 1008-1019, June, 2020
DOI10.1007/s11814-020-0542-1  Export Citation
The influence of the Gemini surfactants hydrocarbon tail on in-situ synthesis of silver nanoparticles: Characterization, surface studies and biological performance
Samy M. Shaban1, 2, and Dong-Hwan Kim1, 2, †
  • 1School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Korea
  • 2Biomedical Institute for Convergence at SKKU (BICS), Sungkyunkwan University, Suwon 16419, Korea
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Three different Gemini compounds containing different lengths of multi-carbonyl groups were synthesized, and the effect of their hydrocarbon tail length on the AgNPs synthesis was investigated. The Gemini surfactants with the long hydrocarbon chain tail produces small AgNPs with a narrow size distribution and high colloidal stability in an aqueous phase. The surface parameters of the aqueous solution were affected by the hydrocarbon chain length as well as phase temperature. The critical micelle concentration, assessed by surface tension and conductometric measurements, decreases with both increasing solution temperature and increasing hydrocarbon tail length. Thermodynamic calculations predicted the ability of the synthesized Gemini surfactant to adsorb on the phase surface and aggregate in a cluster.
Keywords:Multi-carbonyl Gemini Amphiphilic;Surface and Thermodynamic Parameters;AgNPs;Sulfate-reducing Bacteria;Emulsion Stability
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