Selective molecularly imprinted polymer for the analysis of chlorpyrifos in water samples

Oya Aydın Urucu; Asli Beyler Cigil; Hatice Birtane; Ece Kök Yetimoglu; Memet Vezir Kahraman

Journal of Industrial and Engineering Chemistry, Vol.87, 145-151, July, 2020

DOI10.1016/j.jiec.2020.03.025 Export Citation

Selective molecularly imprinted polymer for the analysis of chlorpyrifos in water samples

Oya Aydın Urucu^†, Asli Beyler Cigil¹, Hatice Birtane, Ece Kök Yetimoglu, and Memet Vezir Kahraman^†

Faculty of Arts and Sciences, Department of Chemistry, Marmara University, Istanbul, Turkey
¹Vocational School of Technical Science, Department of Chemistry and Chemical Process Technology, Amasya University, Amasya, Turkey

E-mail:,

In this paper, a new molecularly imprinted solid-phase extraction (MISPE) method was described for the determination of the chlorpyrifos in water samples. A thiol-ene based UV-cured polymer was prepared by mixing glyoxal bis (-diallyl acetal), pentaerythritol tetrakis (3-mercaptopropionate), polyethylene glycol diacrylate (PEGDA), and photoinitiator. Chlorpyrifos was added to the prepared polymer as a template analyte, and its analysis was performed by gas chromatography with mass detection (GC-MS). The influence of some analytical parameters was studied. We found that the use of the molecularly imprinted polymer (MIP) UV-cured disc provides an easy, selective, and available solution for removing chlorpyrifos from water samples.

Keywords:Selective removal;Thiol-ene;Molecularly imprinted polymers;Water treatment;UV-cured polymer

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[2] Bian Y, Liu F, Chen F, Sun P, Food Chem., 250, 230 (2018)

[3] Zhu J, Wang J, Ding Y, Liu B, Xi W, Ecotoxicol. Environ. Saf., 149, 26 (2018)

[4] Newton I, Organochlorine Pesticides, Rachel Carson, and the Environmental Movement, 5, pp.97 (2018).

[5] Alfonso LF, German GV, Carmen PCM, Hossein G, Chemosphere, 166, 292 (2017)

[6] Diaz-Cruz MS, Barcelo D, J. Chromatogr. A, 1132, 21 (2006)

[7] Sang ZY, Wang YT, Tsoi YK, Leung KSY, Food Chem., 136, 710 (2013)

[8] Shaikh H, Andac M, Memon N, Bhanger MI, Nizamani SM, Denizli A, RSC Adv., 5, 26604 (2015)

[9] Zhang M, Hea J, Shen Y, He W, Li Y, Zhao D, Zhang S, Talanta, 178, 1011 (2018)

[10] Binsalom A, Chianella I, Campbell K, Zourob M, J. Chromatogr. Sep. Tech., 7, 1 (2016)

[11] Yao W, Wang S, Xu B, Yin H, Gao Z, Int. J. Mater. Sci. Appl., 5, 160 (2016)

[12] Liu J, Yang M, Huai LF, Chen YT, 4th International Conference on Bioinformatics and Biomedical Engineering, (2010).

[13] Li G, Row KH, Sep. Purif. Rev., 47, 1 (2018)

[14] Cigil AB, Cankurtaran H, Kahraman MV, React. Funct. Polym., 114, 75 (2017)

[15] Cakmakci E, Yuce-Dursun B, Demir S, React. Funct. Polym., 111, 38 (2017)

[16] Cakmakci E, Mulazim Y, Kahraman MV, Apohan NK, React. Funct. Polym., 71(1), 36 (2011)

[17] Urucu OA, Yetimoglu EK, Devecioglu D, Int. J. Adv. Eng. Pure Sci., 30(4), 398 (2018)

[18] Pirozzi D, Fanelli E, Aronne A, Pernice P, Mingione A, J. Mol. Catal. B-Enzym., 59, 116 (2009)

[19] Anirudhan TS, Alexander S, J. Chem. Technol. Biotechnol., 88(10), 1847 (2013)

[20] Zhong S, Kong Y, Zhou L, Zhou C, Zhang X, Wang Y, J. Chromatogr. B, 945, 39 (2014)

[21] Sanagi MM, Salleh S, Ibrahim WAW, Naim AA, Malays. J. Anal. Sci., 15, 175 (2011)

[22] Sanagi MM, Salleh S, Ibrahim WAW, Naim AA, Hussain DHMMI, Aboul-Enein HY, J. Food Comp. Anal., 32(2), 155 (2013)

[23] Zhou M, Hu N, Shu S, Wang M, Anal J, Methods Chem., 2015, 385167 (2015)

[24] Barros LA, Custodio R, Rath S, Braz. Chem. Soc., 27, 2300 (2016)