화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.87, 162-172, July, 2020
DOI10.1016/j.jiec.2020.03.033  Export Citation
Synthesis of heterogenized polyoxometalate-based ionic liquids with Bronsted-Lewis acid sites: A magnetically recyclable catalyst for biodiesel production from low-quality oils
Wenlei Xie†, and Hao Wang
  • School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, PR China
E-mail:
The aim of this study is to develop a magnetically recyclable acid catalyst for biodiesel production from low-quality acidic oils. To achieve this, polyoxometalate (POM)-based sulfonated ionic liquids (ILs) bearing Bronsted-Lewis acid sites, namely (Py-Ps)PMo, were firstly prepared by reaction of pyridine with 1,3-propanesultone, followed by anion exchange with phosphomolybdic acid (HPMo). Thereafter, the soprepared ILs were loaded on the amino-functionalized metal.organic framework (CoFe2O4/MIL-88B(Fe)- NH2) to synthesize the recoverable solid catalyst. The obtained CoFe2O4/MIL-88B(Fe)-NH2/(Py-Ps)PMo catalyst was characterized by several techniques, which provided an evidence that the acidic ILs were loaded on the magnetic support by strong charge interaction effect. This catalyst showed highly catalytic activities toward the transesterification of soybean oil and esterification of free fatty acids (FFAs), making it to be applicable for one-pot production of biodiesel from low-quality acidic oils. The catalytic performance was originated from the combination of the characteristics of Bronsted-Lewis acid sites and porous structure of the support. Moreover, the catalyst could be simply recovered by a permanent magnet and reutilized for several times with no remarkable attenuation of catalytic activity. Thus, the IL based solid catalyst possessed the potential of efficient and environmentally benign production of biodiesel practically from the low-quality oils.
Keywords:Biodiesel;Heterogeneous catalyst;Ionic liquid;Phosphomolybdic acid;Metal.organic framework;Magnetic particle
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