화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.31, No.3, 267-276, June, 2020
DOI10.14478/ace.2020.1010  Export Citation
양이온 개환중합에 의한 폴리알킬렌 옥사이드 코폴리올의 합성과 아지드화 코폴리올의 특성 연구
Synthesis of Characterization of Poly(alkylene oxide) Copolyols by Catioinc Ring Opening Polymerization and Their Azide Functionalized Copolyols
이재명, 설양호1, 권정옥1, 진용현2, 노시태†
  • 한양대학교 재료화학공학과
  • 1풍원화학(주)
  • 2제이캠(주)
Jae-Myung Lee, Yang-Ho Seol1, Jung-Ok Kwon1, Yong-Hyun Jin2, and Si-Tae Noh†
  • Department of Material & Chemical Engineering, Hanyang University, Ansan 15588, Korea
  • 1Poongwon Chemical Co, Ltd, Polymer R&D Center, Ansan 15420, Korea
  • 2Hanyang Business Incubator, J-Chem, Ansan 15588, Korea
E-mail:
초록
Oxirane계 단량체의 양이온 개환 공중합반응으로 합성되는 ECH (ephichorohydrin) 기반 copolyol (PECH copolyol)류의 특성에 대한 반응온도, 용매의 종류 및 개시제에 대한 영향을 연구하였다. 공단량체로는 butylene oxide와 hexylene oxide 두 종류의 알킬렌 옥사이드를 사용하였으며, 중합 조건은 methylene chloride (MC) 용매에서 개시제로 diethylene glycol (DEG)를 사용한 조건과 toluene을 용매에서 tripropylene glycol (TPG)를 개시제로 사용한 두 조건으로 진행하였다. 개환 공중합반응에서 active monomer (AM) mechanism 유도를 위해 단량체는 실린지 펌프를 사용해 IMA (increased monomer addition) 방법으로 주입하였고 중합온도는 -5 ℃에서 실행하였다. 합성된 ephichorohydrin (ECH) 기반 copolyol 인 PECH copolyol은 치환반응으로 ECH unit를 아지드화하여 glycidyl azide계 에너지 함유 copolyol (GAP copolyol)로 전환하였다. 합성된 아지드화 코폴리올은 용매와 개시제의 변화에 대한 영향은 크지 않았으며, 분자량은 아지드화 반응 후 평균 500 증가함으로써 GAP 코폴리올이 설계한 대로 중합되었음을 확인하였다. DSC 분석으로 copolyol류의 조성비 변화에 따른 유리전이 온도(glass transition temperature, Tg)의 변화를 측정하였을 때, 공단량체의 함량이 증가할 수록 알킬 사슬의 길이에 의한 영향으로 Tg와 점도가 모두 감소하는 경향을 보였다. 아지드화 반응과정에서 생성되는 CH3N3의 생성을 원천적으로 방지할 수 있으며, 대규모 공정이 가능할 것으로 기대된다.
Poly(epichlorohydrin) copolyol series (PECH copolyols) were synthesized via cationic ring-opening copolymerization (ROCP) of oxirane-based monomers and effects of reaction temperature, solvent type, and initiator were studied. As a comonomer, two types of alkylene oxides were used, and polymerization conditions were conducted both with diethylene glycol (DEG) as an initiator in methylene chloride (MC) solvent and tripropylene glycol (TPG) in toluene solvent. In order to induce the active monomer (AM) mechanism in the ring-opening copolymerization reaction, the monomer was injected by an incremental monomer addition (IMA) method using a syringe pump, and the polymerization was performed at -5 ℃. PECH copolyol, a synthesized ephichorohydrin (ECH)-based copolyol, was converted to glycidyl azide-based energy-containing copolyol (GAP copolyol) by azadizing the ECH unit through a substitution reaction. It was confirmed that the synthesized azide copolyol had little effects on changes of the solvent and the initiator. Also, the molecular weight increased 500 after the azide reaction, thereby the GAP copolyol was polymerized as designed. As the content of the comonomer increased, both the Tg and viscosity tended to decrease due to the influence of the alkyl chain length. It is possible to fundamentally prevent CH3N3 amount produced in the azide reaction process, and it is expected that a large-scale process could be achievable.
Keywords:Cationic ring opening polymerization;Poly(epichlorohydrin-co-1,2-butylene oxide) copolyol;Poly(epichlorohydrin-co-1,2-hexylene oxide) copolyol;Azidation
  1. Gaur B, Lochab B, Choudhary V, Varma IK, J. Macromol. Sci.-Polym. Rev, 43(4), 505 (2003)
  2. Cho BS, Noh ST, Macromol. Res., 21(2), 221 (2013)
  3. Kawamoto AM, Holanda JAS, Barbieri U, Polacco G, Keicher T, Krause H, Kaiser M, Propell. Explos. Pyrot., 33(5), 365 (2008)
  4. Diaz E, Brousseau P, Ampleman G, Prud’ homme RE, Propell. Explos. Pyrot., 28(3), 101 (2003)
  5. Frankel MB, Grant LR, Flanagan JE, J. Propul. Power, 8(3), 560 (1992)
  6. Vandenberg EJ, Polyethers containing azidomethyl side chains, US Patent, 3,645,917 (1972).
  7. Ribeiro SP, Santiago DG, Vianna AD, Polimeros, 22(5), 407 (2012)
  8. Ribeiro SP, Santiago DG, Vianna AD, Polimeros, 22, 414 (2012)
  9. Frankel MB, Grant LR, Flanagan JE, J. Propul. Power, 8(3), 560 (1992)
  10. Kawamoto AM, Oliveria JIS, Rezenda LC, Keicher T, Krause H, J. Aerosp. Technol. Manag., 1(1), 35 (2009)
  11. Barbieri B, Polaco G, Massini R, Macromol. Symp., 234, 51 (2006)
  12. Kim JS, Kim DK, Kweon JO, Lee JM, Noh ST, Kim SY, Appl. Chem. Eng., 23, 305 (2013)
  13. Kim HS, You JS, Kweon JO, Kim JS, Lee TS, Noh ST, Jang YO, Kim DK, Kwon SK, Appl. Chem. Eng., 21(4), 377 (2010)
  14. Bohnlein MJ, Krober H, Propell. Explos. Pyrot., 34(3), 239 (2009)
  15. Han XG, Shanks RA, Pavel D, Eur. Polym. J., 41(5), 984 (2005)
  16. Eroglu MS, Hazer B, Guven O, Baysal BM, J. Appl. Polym. Sci., 60(12), 2141 (1996)
  17. Reddy TS, Nair JK, Satpute RS, Gore GM, Sikder AK, J. Appl. Polym. Sci., 118(4), 2365 (2010)
  18. Penczek S, Cypryk M, Duda A, Kubisa P, Slomkowski S, Prog. Polym. Sci, 32(2), 247 (2007)
  19. Al-Kaabi K, Van Reenen AJ, J. Appl. Polym. Sci., 114(1), 398 (2009)
  20. Carlotti S, Labbe A, Rejsek V, Doutaz S, Gervais M, Deffieux A, Macromolecules, 41(19), 7058 (2008)
  21. Penczek S, Kubisa P, Szymanski R, Makromol. Chem., Macromol. Symp., 3, 203-220 (1986).
  22. Parker RE, Isaacs NS, Chem. Rev., 59(4), 737 (1959)
  23. Guanaes D, Bittencourt E, Eberlin MN, Sabino AA, Eur. Polym. J., 43(5), 2141 (2007)
  24. Antelmann B, Chisholm MH, Iyer SS, Huffman JC, Navarro-Llobet D, Pagel M, Simonsick WJ, Zhong WQ, Macromolecules, 34(10), 3159 (2001)
  25. Tokar R, Kubisa P, Penczek S, Dworak A, Macromolecules, 27(2), 320 (1994)
  26. Bednarek M, Kubisa P, Penczek S, Macromolecules, 32(16), 5257 (1999)
  27. Eroglu MS, Guven O, J. Appl. Polym. Sci., 60(9), 1361 (1996)
  28. Bednarek M, Biedron T, Kaluzynski K, Kubisa P, Pretula J, Penczek S, Macromol. Symp., 157, 1 (2000)