화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.37, No.7, 1258-1265, July, 2020
DOI10.1007/s11814-020-0537-y  Export Citation
Solid-state conversion of metal oleate precursors for the preparation of LiNi1/3Co1/3Mn1/3O2 as cathode material for lithium-ion batteries
Dongyub Kwak, Won-Gwang Lim1, Kyuchul Shin, In Woo Cheong†, Jinwoo Lee1, †, and Jin Joo†
  • Department of Applied Chemistry, Kyungpook National University, Daegu 41566, Korea
  • 1Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST),, Daejeon 34141, Korea
E-mail:, ,
A solid-state conversion process for the preparation of LiNi1/3Co1/3Mn1/3O2 (NCM333) using metal oleate precursors was studied. The low melting points of metal oleate complexes result in a highly homogeneous mixture of Li-, Ni-, Co-, and Mn-oleates before calcination at a high temperature in a solid-state conversion process. The discharge capacity and capacity retention were assessed using a control sample prepared with metal acetate precursors. Cyclic voltammetry and electrochemical impedance spectroscopy showed larger cathodic and anodic peak currents and a lower charge transfer resistance for the coin cell with the cathode prepared from metal oleates than for the cell with the cathode prepared from metal acetates. The superior electrochemical properties of the NCM333 cathode prepared by the solid-state conversion process suggested in this study are attributed to the formation of a perfect R3m layered structure with a low degree of cation mixing.
Keywords:Solid-state Conversion;Lithium Ion Battery;Cathode;Cation Mixing;Layered Structure
  1. Armand M, Tarascon JM, Nature, 451, 652 (2008)
  2. Tarascon JM, Armand M, Nature, 414, 359 (2001)
  3. Peters JF, Baumann M, Zimmermann B, Braun J, Weil M, Renew. Sust. Energ. Rev., 67, 491 (2017)
  4. Su L, Jing Y, Zhou Z, Nanoscale, 3, 3967 (2011)
  5. Cheng FY, Liang J, Tao ZL, Chen J, Adv. Mater., 23(15), 1695 (2011)
  6. Lim WG, Jo CS, Lee JW, Hwang DS, Korean J. Chem. Eng., 35(2), 579 (2018)
  7. Lim JE, Kim JK, Korean J. Chem. Eng., 35(12), 2464 (2018)
  8. Cui X, Wang S, Mao L, Wang P, Li Z, Wang S, Li S, Electrochim. Acta, 337, 135709 (2020)
  9. Ko HS, Park HW, Kim GJ, Lee JD, Korean J. Chem. Eng., 36(4), 620 (2019)
  10. Schipper F, Erickson EM, Erk C, Shin JY, Chesneau FF, Aurbach D, J. Electrochem. Soc., 164(1), A6220 (2017)
  11. Vu DL, Lee JW, Korean J. Chem. Eng., 33(2), 514 (2016)
  12. Wang Y, Chen Y, Cheng S, He L, Korean J. Chem. Eng., 28(3), 964 (2011)
  13. Doh CH, Jin BS, Lim JH, Moon SI, Korean J. Chem. Eng., 19(5), 749 (2002)
  14. Li S, Zhu K, Liu J, Zhao D, Cui X, J. Electrochem. Energy, 16, 011006 (2019)
  15. Wang J, Yao X, Zhou X, Liu Z, J. Mater. Chem., 21, 2544 (2011)
  16. Shin YJ, Choi WJ, Hong YS, Yoon S, Ryu KS, Chang SH, Solid State Ion., 177(5-6), 515 (2006)
  17. Santhanam R, Rambabu B, J. Power Sources, 195(13), 4313 (2010)
  18. Kim MG, Shin HJ, Kim JH, Park SH, Sun YK, J. Electrochem. Soc., 152(7), A1320 (2005)
  19. Idemoto Y, Matsui T, Solid State Ion., 179(17-18), 625 (2008)
  20. Wu F, Wang M, Su YF, Bao LY, Chen S, J. Power Sources, 195(9), 2900 (2010)
  21. Lee KS, Myung ST, Sun YK, J. Power Sources, 195(18), 6043 (2010)
  22. Li J, Cao C, Xu X, Zhu Y, Yao R, J. Mater. Chem. A, 1, 11848 (2013)
  23. Fujii Y, Miura H, Suzuki N, Shoji T, Nakayama N, J. Power Sources, 171(2), 894 (2007)
  24. Chang ZR, Chen ZJ, Wu F, Yuan XZ, Wang HJ, Electrochim. Acta, 54(26), 6529 (2009)
  25. Yu C, Li GS, Guan XF, Zheng J, Li LP, Chen TW, Electrochim. Acta, 81, 283 (2012)
  26. Kiziltas-Yavuz N, Herklotz M, Hashem AM, Abuzeid HM, Schwarz B, Ehrenberg H, Mauger A, Julien CM, Electrochim. Acta, 113, 313 (2013)
  27. Huang ZD, Liu XM, Oh SW, Zhang B, Ma PC, Kim JK, J. Mater. Chem., 21, 10777 (2011)
  28. Li C, Hou Q, Li S, Tang F, Wang P, J. Alloy. Compd., 723, 887 (2017)
  29. Ryu WH, Lim SJ, Kim WK, Kwon H, J. Power Sources, 257, 186 (2014)
  30. Wu F, Wang M, Su YF, Bao LY, Chen S, J. Power Sources, 195(8), 2362 (2010)
  31. Xie J, Huang X, Zhu Z, Dai J, Ceram. Int., 36, 2485 (2010)
  32. Sinha NN, Munichandraiah N, J. Electrochem. Soc., 157(6), A647 (2010)
  33. Shaju KM, Bruce PG, Adv. Mater., 18(17), 2330 (2006)
  34. Ding CX, Meng QS, Wang L, Chen CH, Mater. Res. Bull., 44(3), 492 (2009)
  35. Ding Y, Zhang P, Long Z, Jiang Y, Gao D, J. Alloy. Compd., 462, 340 (2008)
  36. Lu CH, Lin YK, J. Power Sources, 189(1), 40 (2009)
  37. Lee JW, Lee JH, Viet TT, Lee JY, Kim JS, Lee CH, Electrochim. Acta, 55(8), 3015 (2010)
  38. Jiang X, Sha Y, Cai R, Shao Z, J. Mater. Chem. A, 3, 10536 (2015)
  39. He P, Wang HR, Qi L, Osaka T, J. Power Sources, 160(1), 627 (2006)
  40. Li DC, Muta T, Zhang LQ, Yoshio M, Noguchi H, J. Power Sources, 132(1-2), 150 (2004)
  41. Wang LQ, Hao LF, Yuan HT, Guo J, Zhao M, Li HX, Wang YM, J. Power Sources, 162(2), 1367 (2006)
  42. Ohzuku T, Makimura Y, Chem. Lett., 30(7), 642 (2001)
  43. Huang YY, Chen JT, Ni JF, Zhou HH, Zhang XX, J. Power Sources, 188(2), 538 (2009)
  44. Yabuuchi N, Ohzuku T, J. Power Sources, 119-121, 171 (2003)
  45. Belharouak I, Sun YK, Liu J, Amine K, J. Power Sources, 123(2), 247 (2003)
  46. Park J, An KJ, Hwang YS, Park JG, Noh HJ, Kim JY, Park JH, Hwang NM, Hyeon T, Nat. Mater., 3(12), 891 (2004)
  47. Rodriguez-Carvajal J, Physica B, 192, 55 (1993)
  48. Roisnel T, Rodriguez-Carvajal J, Mater. Sci. Forum, 378-381, 118 (2001)
  49. Breger J, Dupre N, Chupas PJ, Lee PL, Proffen T, Parise JB, Grey CP, J. Am. Chem. Soc., 127(20), 7529 (2005)
  50. Ohzuku T, Nakura K, Aoki T, Electrochim. Acta, 45(1-2), 151 (1999)
  51. Zhang B, Chen G, Xu P, Li CC, J. Power Sources, 176(1), 325 (2008)
  52. Deng C, Zhang S, Wu B, Yang SY, Li HQ, J. Solid State Electrochem., 14, 871 (2010)
  53. Zhang XY, Jiang WJ, Mauger A, Qilu, Gendron F, Julien CM, J. Power Sources, 195(5), 1292 (2010)
  54. Zhao E, Chen M, Chen D, Xiao X, Hu Z, ACS Appl. Mater. Interfaces, 7, 27096 (2015)
  55. Yang C, Zhang X, Huang M, Huang J, Fang Z, ACS Appl. Mater. Interfaces, 9, 12408 (2017)
  56. Park JH, Cho JH, Kim SB, Kim WS, Lee SY, Lee SY, J. Mater. Chem., 22, 12574 (2012)
  57. Zhang LL, Li Z, Yang XL, Ding XK, Zhou YX, Sun HB, Tao HC, Xiong LY, Huang YH, Nano Energy, 34, 111 (2017)
  58. Zhang QY, Su YF, Chen L, Lu Y, Bao LY, He T, Wang J, Chen RJ, Tan J, Wu F, J. Power Sources, 396, 734 (2018)