Here, the synthesis of RuO2 loaded CeO2 with varying amount of Ru loading with enhanced amount of Ce3+ and surface area, through synthesis of CeO2 using cerium ammonium carbonate complex as procure followed by Ru loading by impregnation and calcination at 300 degrees C, is presented. Corresponding characterizations by XRD, SEM, TEM, XPS of all the samples reveal the formation of highly crystalline mesoporous CeO2 nanoparticles with uniformly dispersed RuO2 particles on the CeO2 surface having approximately 45% Ce3+. All the samples were utilized as oxygen evolution reaction (OER) catalyst for electrocatalytic H-2 generation through water electrolysis. Electrocatalytic experiments reveal that synthesized 1 wt% RuO2 loaded CeO2 (1-RuO2/CeO2) showed superior OER activity. A quite low over-potential of 350 mV is required to attain a current density of 10 mA/cm(2) (eta(10)), with a Tafel slope of 74 mVdec(-1) for OER in 1 M KOH solution. The synthesized 1-RuO2/CeO2 electrocatalyst also exhibited superior long term stability in basic medium and redox atmosphere. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.