과붕산나트륨 양극 활물질 첨가에 따른 차량용 납산배터리 성능 특성

임태섭; 김성준; 김상동; 양승철; 정연길; Tae Seop Lim; Sung Jun Kim; Sang Dong Kim; SeungCheol Yang; Yeon-Gil Jung

Korean Journal of Materials Research, Vol.30, No.8, 426-434, August, 2020

DOI10.3740/MRSK.2020.30.8.426 Export Citation

과붕산나트륨 양극 활물질 첨가에 따른 차량용 납산배터리 성능 특성

Performance Characteristics of Lead Acid Battery with the Contents of Sodium Perborate Tetrahydrate (SPT) in Positive Plate Active Material

임태섭^{1, 2}, 김성준^{1, 2}, 김상동¹, 양승철^{2, †}, 정연길^{2, †}

¹세방전지㈜
²창원대학교 신소재공학부

Tae Seop Lim^{1, 2}, Sung Jun Kim^{1, 2}, Sang Dong Kim¹, SeungCheol Yang^{2, †}, and Yeon-Gil Jung^{2, †}

¹Sebang Global battery Co., Ltd., Changwon, Republic of Korea
²School of Nano & Advanced Materials Eng., Changwon National Univ., Changwon, Republic of Korea

E-mail:,

The performance characteristics of a lead acid battery are investigated with the content of Sodium Perborate Tetrahydrate (SPT, NaBO3·4H2O) in a positive plate active material. SPT, which reacts with water to form hydrogen peroxide, is applied as an additive in the positive plate active material to increase adhesion between the substrate (positive plate) and the active material; this phenomenon is caused by a chemical reaction on the surface of substrate. A positive plate with the increasing content of SPT is prepared to compare its properties. It is confirmed that the oxide layer increases at the interface between the substrate and the active material with increasing content of SPT; this is proven to be an oxide layer through EDS analysis. Battery performance is confirmed: when SPT content is 2.0 wt%, the charging acceptance and high rate discharge properties are improved. In addition, the lifetime performance according to the Standard of Battery Association of Japan (SBA) S0101 test is improved with increasing content of SPT.

Keywords:lead-acid battery;SPT;positive plate;active material;electrode

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[4] Sawai K, Ohmae T, Suwaki H, Shiomi M, Osumi S, J. Power Sources, 174(1), 54 (2007)

[5] Pavlov D, Naidenov V, Milusheva Y, Vassilev S, Shibahara T, Tozuka M, J. Energy Storag, 17, 336 (2018)

[6] Zhang SK, Zhang H, Cheng J, Zhang WF, Cao GP, Zhao HL, Yang YS, J. Power Sources, 334, 31 (2016)

[7] Ebner E, Burow D, Borger A, Wark M, Atanassova P, Valenciano J, J. Power Sources, 239, 483 (2013)

[8] Fernandez M, Valenciano J, Trinidad F, Munoz N, J. Power Sources, 195(14), 4458 (2010)

[9] Sugumaran N, Everill P, Swogger SW, Dubey DP, J. Power Sources, 279, 281 (2015)

[10] Moncada A, Piazza S, Sunseri C, Inguanta R, J. Power Sources, 275, 181 (2015)

[11] Foudia M, Matrakova M, Zerroual L, J. Power Sources, 279, 146 (2015)

[12] Deyab MA, J. Power Sources, 390, 176 (2018)

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