This study demonstrates a novel "Gas Switching Water Splitting (GSWS)" technology for production of pure H-2 with integrated CO2 capture. The reactor concept is based on the chemical looping technology where an oxygen carrier (metal oxide) is used to transport O-2 from air to the fuel for different redox reactions. Unlike the conventional chemical looping, Gas Switching Technology inherently avoids external circulation of the oxygen carrier by alternating the oxidizing and reducing gases in a single bubbling fluidized bed reactor. This greatly simplifies reactor design leading to easier scale-up of the technology in comparison with the conventional chemical looping. The first experimental demonstration of the GSWS concept was completed at atmospheric pressure and temperatures ranging between 700 degrees C and 900 degrees C with iron-based oxygen carrier supported on alumina (similar to 35wt% Fe2O3 on Al2O3). Approximately 99% H-2 purity was achieved at similar to 80% oxygen utilization. Significant fuel slippage was observed especially beyond 33% degree of reduction with some carbon deposition. The deposited carbon was able to combust/gasify completely in the subsequent air stage which makes the concept robust in sustaining oxygen carrier life. However, the gas mixing between the GSWS stages reduced the H-2 purity, CO2 purity, and CO2 capture efficiency. Tominimize the negative impact of gasmixing, Cu doped Mg(Fe0.9Al0.1)(2)O-4 spinel with 74wt% active content was developed specifically for the second experimental demonstration. Despite the high stability and reactivity under redox conditions with TGA, this oxygen carrier did not perform optimally in 5 cm ID fluidized bed reactor because of excessive agglomeration at degree of reduction beyond 34%. In general, a range of the active content between 35 and 70 wt% of the oxygen carrier was desired for optimal performance of the GSWS concept. (C) 2020 The Authors. Published by Elsevier B.V.