The continuous increase in primary energy demand and the decrease in the availability of fossil fuels were led to a condition of energy security concerns. In this context, hydrogen can be seen as a promising energy carriers. This paper investigated the environmental performance, through Life Cycle Assessment (LCA) methodology, of a combined production system of hydrogen and power based on aluminum combustion with water. This system is potentially able to produce the integrated generation of four energy sources: hydrogen, high temperature steam, heat and work at the turbine shaft. The LCA results indicated that the life-cycle phases that determine the main environmental impact are: liquid aluminum production, transports of liquid aluminum and electricity consumption. In addition, the major release of carbon dioxide emissions is due to the use of natural gas in the aluminum production phase. In order to determine the "greener" alternative and support the system design choices, according to the eco-design perspective, different system configurations were investigated. In particular, the reaction mechanism between first primary aluminum powder and water steam and then secondary aluminum at liquid state and water steam. The environmental comparison highlighted that the former layout increases by more than 78% compared to latter one. (C) 2020 Elsevier Ltd. All rights reserved.