화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.31, No.6, 679-687, December, 2020
DOI10.14478/ace.2020.1080  Export Citation
Amine으로 개질된 ZIF-8을 함유한 PEBAX-PEI 복합막의 기체투과 특성
Gas Permeation Characteristics of PEBAX-PEI Composite Membranes Containing ZIF-8 Modified with Amine
이은선, 홍세령1, †
  • 상명대학교 화공신소재학과
  • 1상명대학교 계당교양교육원
Eun Sun Yi, and Se Ryeong Hong1, †
  • Department of Chemical Engineering and Materials Science, Sangmyung University, Seoul 03016, Korea
  • 1Kyedang College of General Educations, Sangmyung University, Seoul 03016, Korea
E-mail:
초록
본 연구에서는 ZIF-8과 amine으로 개질된 ZIF-8 (amineZIF-8) 함량에 따른 PEBAX/ZIF-8-PEI, PEBAX/amineZIF-8-PEI 복합막을 제조하고, 각 복합막에 대해 N2와 CO2의 기체투과 성질을 조사하였다. PEBAX/ZIF-8-PEI 복합막의 N2와 CO2 투과도는 ZIF-8 함량이 증가할수록 증가하였고, CO2/N2 선택도는 점차 감소하였다. PEBAX/amineZIF-8-PEI 복합막의 경우 N2의 투과도는 소폭 감소하였고, CO2는 amineZIF-8 0.5 wt%까지 증가하다가 그 이후의 함량에서는 감소하였으며 CO2/N2 선택도는 amineZIF-8 0.5 wt%에서 78.3으로 가장 높은 선택도를 보였다. AmineZIF-8 0.5 wt%에서 CO2/N2 선택도가 가장 높은 이유는 amine 개질로 인해 PEBAX와 amineZIF-8 사이에서 서로 간의 호환성을 향상시켰고, amineZIF-8 이 PEBAX 내에 고르게 분산되면서 다공성의 ZIF-8 효과와 CO2에 친화성이 있는 amine의 효과를 가장 크게 받았기 때문으로 보인다.
In this study, poly(ether-block-amide) (PEBAX)/zeolitic imidazolate framework-8 (ZIF-8)-polyetherimide (PEI), and PEBAX/ amine-modified ZIF-8 (amineZIF-8)-PEI composite membranes were prepared by varying the contents of ZIF-8 and amineZIF-8. Also the gas permeability properties of N2 and CO2 were investigated for each composite membrane. The N2 and CO2 permeability of the PEBAX/ZIF-8-PEI composite membrane increased as the ZIF-8 content increased, while the CO2/N2 selectivity gradually decreased. In the case of the PEBAX/amineZIF-8-PEI composite membrane, the permeability of N2 decreased slightly, and CO2 increased till amineZIF-8 amount was 0.5 wt% and then decreased when the content increased further. The CO2/N2 selectivity was the highest with a value of 78.3 at 0.5 wt% of amineZIF-8. because the amine modification in the amineZIF-8 improves the compatibility between PEBAX and amineZIF-8, It seems that amineZIF-8 was evenly dispersed in PEBAX, which could be greatly influenced by the porousity of ZIF-8 and also the affinity of amine toward CO2.
Keywords:PEBAX;ZIF-8;Permeability;Selectivity
  1. Ge L, Zhu ZH, Rudolph V, Sep. Purif. Technol., 78(1), 76 (2011)
  2. Akhtar FH, Kumar M, Peinemann KV, J. Membr. Sci., 525, 187 (2017)
  3. Kim H, Korean Chem. Eng. Res., 49(4), 460 (2011)
  4. Zarshenas K, Raisi A, Aroujalian A, J. Membr. Sci., 510, 270 (2016)
  5. Murali RS, Ismail AF, Rahman MA, Sridhar S, Sep. Purif. Technol., 129, 1 (2014)
  6. Melgar VMA, Kim J, Othman MR, J. Ind. Eng. Chem., 28, 1 (2015)
  7. Sridhar S, Suryamurali R, Smitha B, Aminabhavi TM, Colloids Surf. A: Physicochem. Eng. Asp., 297, 267 (2007)
  8. Bondar VI, Freeman BD, Pinnau I, J. Polym. Sci. B: Polym. Phys., 38(15), 2051 (2000)
  9. Car A, Stropnik C, Yave W, Peinemann KV, Sep. Purif. Technol., 62(1), 110 (2008)
  10. Kim H, Lim C, Hong S, J. Sol-Gel Sci. Technol., 36, 213 (2005)
  11. Kim HB, Lee MW, Park WK, Lee SJ, Lee HK, Lee SH, Membr. J., 22, 201 (2012)
  12. Hyung CH, Park CD, Kim KH, Rhim JW, Hwang TS, Lee HK, Membr. J., 22, 404 (2012)
  13. Kim KJ, Park SH, So WW, Ahn DJ, Moon SJ, J. Membr. Sci., 211(1), 41 (2003)
  14. Cong HL, Radosz M, Towler BF, Shen YQ, Sep. Purif. Technol., 55(3), 281 (2007)
  15. Kim H, Korean Chem. Eng. Res., 49(4), 460 (2011)
  16. Hu Q, Marand E, Dhingra S, Fritsch D, Wen J, Wilkes G, J. Membr. Sci., 135(1), 65 (1997)
  17. Li H, Eddaoudi M, O’Keeffe M, Yaghi OM, Nature, 402, 276 (1999)
  18. Park KS, Ni Z, Cote AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, O’Keeffe M, Yaghi OM, Proc. Natl. Acad. Sci. U.S.A., 103, 10186 (2006)
  19. Gong X, Wang Y, Kuang T, ACS Sustainable Chem. Eng., 5, 11204 (2017)
  20. Hayashi H, Cote AP, Furukawa H, O'Keeffe M, Yaghi OM, Nat. Mater., 6(7), 501 (2007)
  21. Sutrisna PD, Hou JW, Li HY, Zhang YT, Chen V, J. Membr. Sci., 524, 266 (2017)
  22. Jomekian A, Behbahani RM, Mohammadi T, Kargari A, J. Nat. Gas Sci. Eng., 31, 562 (2016)
  23. Couck S, Denayer JFM, Baron GV, Remy T, Gascon J, Kapteijn F, J. Am. Chem. Soc., 131(18), 6326 (2009)
  24. Khan IU, Othman MHD, Jilani A, Ismail AF, Hashim H, Jaafa J, Rahman MA, Rehman GU, Arab. J. Chem., 11, 1072 (2018)
  25. Cho KY, An H, Do XH, Choi K, Yoo HG, Jeong HK, Lee JS, Baek KY, J. Mater. Chem. A, 6, 18912 (2018)
  26. Ding R, Zheng W, Yang K, Dai Y, Ruan X, Yan X, He G, Sep. Sci. Technol., 236, 1 (2020)
  27. Martinez F, Sanz R, Orcajo G, Briones D, Yanguez V, Chem. Eng. Sci., 142, 55 (2016)
  28. Nordin NAHM, Racha SM, Matsuura T, Misdan N, Sani NAA, Ismail AF, Mustafa A, RSC Adv., 5, 43110 (2015)
  29. Ward WJ, Browall WR, Salemme RM, J. Membr. Sci., 1, 99 (1976)
  30. Liu L, Chakma A, Feng XS, J. Membr. Sci., 235(1-2), 43 (2004)
  31. Nordin NAHM, Ismail AF, Mustafa A, Goh PS, Rana D, Matsuura T, RSC Adv., 4, 33292 (2014)
  32. Zhang Z, Xian S, Xia Q, Wang H, Li Z, Li J, AlChE J., 59(6), 2195 (2013)
  33. Wang Y, Ren Y, Wu H, Wu X, Yang H, Yang L, Wang X, Wu Y, Liu Y, Jiang Z, J. Membr. Sci., 602, 117970 (2020)
  34. Liu D, Wu Y, Xia Q, Li Z, Xi H, Adsorption, 19, 25 (2013)
  35. Wang S, Cui J, Zhang S, Xie X, Xia W, Mater. Res. Express, 7, 1 (2020)
  36. Ismail H, Pasbakhsh P, Noor AFM, Bakar AA, Polymer Testing, 27, 841 (2008)
  37. Bernardo P, Jansen JC, Bazzarelli F, Tasselli F, Fuoco A, Friess K, Izak P, Jarmarova V, Kacirkova M, Clarizia G, Sep. Purif. Technol., 97, 73 (2012)
  38. Rahman MM, Filiz V, Shishatskiy S, Abetz C, Neumann S, Bolmer S, Khan MM, Abetz V, J. Membr. Sci., 437, 286 (2013)
  39. Ehsani A, Pakizeh M, J. Taiwan Inst. Chem. Eng., 66, 414 (2016)
  40. Scofield JMP, Gurr PA, Kim J, Fu Q, Kentish SE, Qiao GG, J. Membr. Sci., 499, 119 (2016)
  41. Nafisi V, Hagg MB, J. Membr. Sci., 459, 244 (2014)
  42. Xu LW, Xiang L, Wang CQ, Yu J, Zhang LX, Pan YC, Chin. J. Chem. Eng., 25(7), 882 (2017)
  43. Amedi HR, Aghajani M, Microporous Mesoporous Mater., 247, 124 (2017)
  44. Robeson LM, J. Membr. Sci., 320(1-2), 390 (2008)