화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.91, 102-109, November, 2020
DOI10.1016/j.jiec.2020.07.039  Export Citation
Novel copolymers with intrinsic microporosity containing tetraphenyl-bipyrimidine for enhanced gas separation
Xiaocui Han, Jianrui Zhang, Cheng Yue, Jinhui Pang†, Haibo Zhang, and Zhenhua Jiang
  • Laboratory of High Performance Plastics (Jilin University), Ministry of Education. National & Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymer, College of Chemistry, Jilin University, Changchun, 130012, PR China
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The gas separation of polymers of intrinsic microporosity (PIMs) was enhanced by incorporating bipyrimidine (bpy) into the polymer (PIM-bpy-x) through the polycondensation of a novel tetraphenyl-bipyrimidine monomer. The structures of PIM-bpy-x were investigated with 1H NMR and FT-IR. Because of the excellent heat resistance imparted by the tetraphenyl-bipyrimidine unit, PIM-bpy-x displayed better thermal stability than did PIM-1. These polymers displayed large Brunauer-Emmett-Teller (BET) surface areas, ranging from 656 to 728 m2 g-1. The BET surface area of PIM-bpy-5 was 728 m2 g-1, which was similar to that of PIM-1 (774 m2 g-1). PIM-bpy-x exhibited excellent gas separation performance. PIM-bpy-5 showed the highest CO2 permeability (5141 barrer), which was much higher than that of PIM-1 (4234 barrer). The increase in CO2 permeability is due to the affinity between the N-rich bipyrimidine units and CO2. Furthermore, PIM-bpy-x also showed greater resistance to aging than did PIM-1. All of the above indicate that introducing bipyrimidine units into the polymers can enhance the gas separation performance of PIMs.
Keywords:CO2 capture and separation;Tetraphenyl-Bipyrimidine;Polymers of intrinsic microporosity;Membrane
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