화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.91, 263-272, November, 2020
DOI10.1016/j.jiec.2020.08.010  Export Citation
Photo-immobilization of pseudozwitterionic polymers with balanced electrical charge for developing anti-coagulation surfaces
Seungjoo Yi, Jiae Seo, Joonbum Lee, Jin-Sung Park, Yun Chan Kang, and Ji-Hun Seo†
  • Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul, 02841, Republic of Korea
E-mail:
This study aims to develop an economical coating agent that can easily impart excellent anti-coagulative property onto polymer surfaces. To this end, photo-reactable pseudozwitterionic polymer comprising cationic ammonium, anionic carboxylic acid, and photo-reactable phenyl azide group was synthesized via free-radical polymerization. Hydrophilicity, surface charge, surface elemental analysis, and anti-biofouling properties of the coated substrates were evaluated after photo-immobilizing the pseudozwitterionic polymer on the PET substrate. The pseudozwitterionic polymer was successfully immobilized; the coated substrate showed excellent anti-biofouling properties. Photo-immobilization of the pseudozwitterionic polymer was also confirmed to be effective in imparting anti-biofouling property onto the fibrous filtration membrane. The immobilized pseudozwitterionic polymer effectively prevented membrane blockage and safely filtered platelets from blood plasma.
Keywords:Pseudozwitterion;Grafting-to;Anti-biofouling;Anti-coagulation;Phenyl azide;Blood filtration membrane
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