Ready and selective access to 2-arylquinazolines from α-amino acids via a new solvent-free domino transformation under synergistic nano Fe-Mo-Se catalyst

Khang X. Nguyen; Phuc H. Pham; An C.D. Nguyen; Chuc T. Nguyen; Tung T. Nguyen; Phong D. Tran; Nam T.S. Phan

Journal of Industrial and Engineering Chemistry, Vol.92, 96-100, December, 2020

DOI10.1016/j.jiec.2020.08.027 Export Citation

Ready and selective access to 2-arylquinazolines from α-amino acids via a new solvent-free domino transformation under synergistic nano Fe-Mo-Se catalyst

Khang X. Nguyen^{1, 2}, Phuc H. Pham^{1, 2}, An C.D. Nguyen^{1, 2}, Chuc T. Nguyen³, Tung T. Nguyen^{1, 2}, Phong D. Tran^{3, †}, and Nam T.S. Phan^{1, 2, †}

¹Faculty of Chemical Engineering, Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet, District 10, Ho Chi Minh City, Vietnam
²Vietnam National University Ho Chi Minh City, Linh Trung Ward, Thu Duc District, Ho Chi Minh City, Vietnam
³Viet Nam Academy of Science and Technology, University of Science and Technology of Ha Noi, 18 Hoang Quoc Viet, Ha Noi, Vietnam

E-mail:,

A Fe-Mo-Se nanopowder, synthesized by a solvothermal protocol, was utilized as a heterogeneous catalyst for the synthesis of 2-arylquinazolines from DL-α-phenylglycine-based α-amino acids and 2-nitrobenzyl alcohols via domino transformations. High yields and selectivity were achieved under solvent-free conditions. The Fe-Mo-Se catalyst offered considerably higher activity than numerous homogeneous and heterogeneous catalysts. To our best knowledge, this domino reaction is new, and the utilization of iron-molybdenum selenide catalyst in the synthesis of quinazolines was not previously reported.

Keywords:Quinazolines;Aminoacids;Synergistic;Selenide;Molybdenum;Nano catalysis

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