화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.92, 218-225, December, 2020
DOI10.1016/j.jiec.2020.09.008  Export Citation
Synthesis and luminescence properties of β-NaRE0.95Eu0.05F4 (RE¼Y, Lu)
Illariia A. Razumkova1, †, Alexander E. Sedykh2, 3, Yuriy G. Denisenko2, 4, and Klaus Müller-Buschbaum2, 3
  • 1Department of Inorganic and Physical Chemistry, Tyumen State University, 6, Volodarskogo Street, Tyumen, 625003, Russia, Russian Federation
  • 2Institut of Inorganic and Analytic Chemistry, Justus-Liebig University Giessen, Heinrich-Buff-Ring 17, Giessen, D-35392, Germany
  • 3Center for Materials Research (LaMa), Justus-Liebig-University Giessen, Heinrich-Buff-Ring 16, Giessen, D-35392, Germany
  • 4Departmentof General and Special Chemistry Industrial University of Tyumen, 38, Volodarskogo Street, Tyumen, 625000, Russia, Germany
E-mail:
On the base of β-NaYF4 and β-NaLuF4 compounds, optimal synthesis methods were selected to obtain highly crystalline Eu3+-doped compounds in the hexagonal (β) structure. The compounds β-NaY0.95Eu0.05F4 and β-NaLu0.95Eu0.05F4 were synthesized by hydrothermal synthesis. The concentration of Na2EDTA introduced into the reaction system as a modifier affects the shape and size of the product from elongated hexagonal prisms to quartz-like crystals. The thermal behavior of the compounds has been studied; the temperature of the polymorphic transition from hexagonal to cubic structure is 680 °C for β-NaY0.95Eu0.05F4 and 624 °C for β-NaY0.95Eu0.05F4, the melting point of α-NaRE0.95Eu0.05F4 is about 900 °C. Under excitation with UV-light of l = 393 nm, β-NaY0.95Eu0.05F4 and β-NaLu0.95Eu0.05F4 show the emission lines of direct Eu3+ f-f transitions, with the presence of the emission from higher Eu3+ excited states (up to 5H3) in both samples, which is responsible for the more orange color of emission instead of the usual red for Eu3+. Emission decay times are slightly longer for β-NaY0.95Eu0.05F4 than for β-NaLu0.95Eu0.05F4, which is the result of a bigger unit cell for the former, leading to longer interatomic distances between Eu3+ ions in the lattice. The luminescence mechanisms for the doped lanthanide ions were thoroughly analyzed.
Keywords:Rare earth fluoride;Synthesis;Luminescence properties
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