화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.38, No.2, 411-421, February, 2021
DOI10.1007/s11814-020-0726-8  Export Citation
Layer-by-layer of graphene oxide-chitosan assembly on PVA membrane surface for the pervaporation separation of water-isopropanol mixtures
Shivshankar Chaudhari, KieYong Cho, SoHyan Joo, ByeongYun An, SongEun Lee, SeonYong Yun, GiJung Lee, JiHyeon Park, MinYoung Shon†, and YouIn Park1
  • Department of Industrial Chemistry, Pukyong National University, San 100, Yongdang-dong, Nam-gu, Busan 48547, Korea
  • 1Center for Membranes, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 34114, Korea
E-mail:
A graphene oxide/chitosan polyelectrolyte layer was used to modify the surface of a polyvinyl alcohol/tetraethyl orthosilicate membrane by layer-by-layer interfacial complexation and, thus, improve the pervaporation characteristics. The interfacial complexation between the chitosan and graphene oxide was confirmed by Fourier-transform infrared and X-ray photoelectron spectroscopy; the changes in surface hydrophilicity after layer-by-layer modification were examined by contact angle measurements, and the morphology of the layer-by-layer membrane was elucidated by field-emission scanning electron microscopy analysis. The pervaporation performance of the modified membranes was evaluated by performing the separation of water-isopropanol (IPA) azeotropes under different operating conditions. In the pervaporation experiments, the best performance was obtained using a membrane with 15 chitosan-GO layers (denoted 15 L-L(CH-GO)). For this membrane, the flux increased from 13.6 to 76.4 g/m2h and the separation factor decreased from 56,720 to 4,001 as the feed temperature was varied from 30 to 60 °C for an 80 : 20 (w/w) IPA/water feed. The apparent permeation activation energies were calculated and that of IPA (122.8 kJ/mol) was greater than that of water (47.4 kJ/mol).
Keywords:Poly(Vinyl Alcohol) (PVA);Chitosan;Layer by Layer;Graphene Oxide;Pervaporation;Surface Modification
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