면섬유 고정제를 위한 양이온 수용성 폴리우레탄의 합성 및 응용

Zhiwei Xu; Xiangdong Zhou

Polymer(Korea), Vol.45, No.1, 1-11, January, 2021

DOI10.7317/pk.2021.45.1.1 Export Citation

면섬유 고정제를 위한 양이온 수용성 폴리우레탄의 합성 및 응용

Synthesis and Application of Cationic Waterborne Polyurethane as Fixing Agent for Cotton Fabric

Zhiwei Xu^{1, 2}, and Xiangdong Zhou^{1, 2, †}

¹College of Textile and Clothing Engineering, Soochow University, Suzhou 215021, China
²National Engineering Laboratory for Modern Silk, Suzhou 215123, China

E-mail:

The traditional reactive dyeing of cotton has the disadvantage of poor fastness. In order to improve the fastness, a novel environment-friendly cationic waterborne polyurethane (CWPU) was successfully synthesized via step-by-step polymerization. The CWPU was prepared from isophorone diisocyanate (IPDI), polypropylene glycol (PPG-1000), methyl ethyl ketone oxime and hydrophilic monomer (EGDEA). The chemical structure of CWPU was characterized by Fourier transform infrared spectroscopy. Effects of n (IPDI/PPG-1000), EGDEA dosage, and the neutralizational degree on the properties of the waterborne polyurethane emulsion and the fastness of the treated dyed cotton fabrics were investigated. Particle size and zeta potential were tested to evaluate the emulsion stability. Scanning electron microscope showed that CWPU had been successfully finished on the fabric. Compared with the untreated cotton fabric, the dry and wet rubbing fastness of the treated cotton fabric dyed with reactive dyes increase 0~0.5 and 0.5~1 level, respectively, and the wash fastness increases 0.5~1 level.

Keywords:polyurethane;cation;fixing agent;reactive dyes;cotton fabric

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[2] Burkinshaw S, Mignanelli M, Froehling P, Bide M, Dyes Pigment., 47, 259 (2000)

[3] Hashem MM, Color. Technol., 122, 135 (2006)

[4] Evans GE, Shore J, Stead CV, J. Soc. Dyers Colour, 100, 304 (1984)

[5] Lee CH, Tang AYL, Wang Y, Kan CW, Dyes Pigment., 161, 51 (2019)

[6] Siddiqua U, Ali H, Iqbal S, Hussain M, Relationship T, J. Mol. Liq., 241, 839 (2017)

[7] Bhuiyan RMA, Hossain MA, Zakaria M, Islam MN, Uddin MZ, J. Polym. Environ., 25, 334 (2017)

[8] Shu D, Fang K, Liu X, Cai Y, Zhang X, Zhang J, J. Clean Prod., 196, 935 (2018)

[9] Chen L, Wang B, Ruan X, Chen J, Yang Y, J. Clean Prod., 107, 550 (2015)

[10] Riaz B, Dilshad H, Muhammad NUH, Rajput AW, Rana A, Ind. Textila., 70, 25 (2019)

[11] Luo Y, Pei L, Zhang H, Zhong Q, Wang J, Polymers, 11, 1854 (2019)

[12] El-Molla M, Helmy M, El-Mahdey FAE, Egypt. J. Chem., 63, 37 (2020)

[13] Nallathambi A, Rengaswami AGD, Carbohydr. Polym., 152, 1 (2016)

[14] Choi HJ, Choe H, Seo WJ, Kim JH, Polym. Korea, 43(4), 532 (2019)

[15] Liu L, Yao J, Fiber. Polym., 12, 42 (2011)

[16] Mughal JM, Saeed R, Naeem M, Ahmed AM, Yasmien A, Siddiqui Q, Iqbal M, J. Saudi Chem. Soc., 17, 23 (2013)

[17] Liu Y, Zhao X, Fibres Text. East. Eur., 25, 96 (2017)

[18] Akindoyo JO, Beg MDH, Ghazali S, Islam MR, Jeyaratnam N, Yuvaraj AR, RSC Adv., 6, 114453 (2016)

[19] Xinrong S, Nanfang W, Kunyang S, Sha D, Zhen C, J. Ind. Eng. Chem., 20(5), 3228 (2014)

[20] Liang H, Liu L, Lu J, Chen M, Zhang C, Ind. Crop. Prod., 117, 169 (2018)

[21] Santamaria-Echart A, Fernandes I, Ugarte L, Barreiro F, Arbelaiz A, Corcuera MA, Eceiza A, Compos. Pt. B-Eng, 137, 31 (2018)

[22] Jimenez-Pardo I, Sun P, van Benthem RATM, Esteves ACC, Eur. Polym. J., 101, 324 (2018)

[23] Spirkova M, Hodan J, Kredatusova J, Poreba R, Uchman M, Serkis-Rodze M, Prog. Org. Coat., 123, 53 (2018)

[24] Li R, Loontjens RJA, Shan Z, Eur. Polym. J., 112, 423 (2019)

[25] Sardon H, Irusta L, Gonzalez A, Fernandez-Berridi MJ, Prog. Org. Coat., 76, 1230 (2013)

[26] Wang ZM, Gao DB, Yang JW, Chen YL, J. Appl. Polym. Sci., 73(14), 2869 (1999)

[27] Dong C, Xin W, Luo Y, RSC Adv., 8, 42041 (2018)

[28] Morel A, Salaun F, Bedek G, Dupont D, Giraud S, J. Mater. Sci., 52(2), 1014 (2017)

[29] Guo Y, Guo J, Miao H, Teng L, Huang Z, Prog. Org. Coat., 77, 988 (2014)

[30] Yang W, Cheng X, Wang HB, Liu YS, Du ZL, Polymer, 133, 68 (2017)

[31] Ge Z, Luo Y, Prog. Org. Coat., 76, 1522 (2013)

[32] Xu LL, Guo MX, Liu S, Bian SW, RSC Adv., 5, 25244 (2015)

[33] Liu ZQ, Tian YH, Kang SM, Zhang XJ, J. Appl. Polym. Sci., 125(5), 3490 (2012)

[34] Chang J, Wang X, Shao J, Li X, Xin W, Luo Y, Coatings, 10, 494 (2020)

[35] Wang HH, Lin MS, J. Polym. Res., 7, 81 (2000)