화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.93, 117-137, January, 2021
DOI10.1016/j.jiec.2020.10.011  Export Citation
Recent advances on the adsorption of herbicides and pesticides from polluted waters: Performance evaluation via physical attributes
Joshua O. Ighalo1, 2, Adewale George Adeniyi1, and Adedeji A. Adelodun3, 4, †
  • 1Department of Chemical Engineering, Faculty of Engineering and Technology, University of Ilorin, Ilorin, Nigeria
  • 2Department of Chemical Engineering, Nnamdi Azikiwe University, P. M. B. 5025, Awka, Nigeria
  • 3Environmental Engineering and Management Research Group, Ton Duc Thang University, Ho Chi Minh City, Viet Nam, Vietnam
  • 4Faculty of Environment and Labour Safety, Ton Duc Thang University, Ho Chi Minh City, Viet Nam, Vietnam
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Due to the need to ameliorate the incessant presence of herbicides and pesticides (H & P) in our waters, we appraised the recent advances in using adsorption technology. Of the numerous adsorbents, montmorillonite and activated carbon (AC) cloth showed the highest adsorption capacity (q) of 1067 and 421.6 mg/g for 2,4-D herbicide and aldicarb, respectively. However, atrazine and aldrin (the most researched H & P, respectively) were best removed using eucalyptus bark-derived biosorbent (936.1 mg/g) and acid-treated patellidae shells (208.3 mg/g), respectively. We carried out further investigation into two newly derived adsorption attributes (effective surface area (eSBET) and preferential adsorption (qp). The eSBET correlates more strongly with q than the conventional specific surface area (SBET) because surface chemistry influences the former. Likewise, qp is a more reliable attribute than q because qp considers the adsorbent's chemical properties and adsorbate’s solubility. The correlation between eSBET and qp was strongest for 2,4-D (95%) and AC (62.25%). Future research could use spent heavy metal adsorbents and photo-assisted adsorption to improve the removal of competitive adsorptives (H & P). Conclusively, adsorption is excellent for mitigating H & P pollution, and the novel adsorption attributes provided here would aid more liable performance optimization.
Keywords:Preferential adsorption;Effective surface area;Herbicides;Pesticides;Water pollution;Surface chemistry
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