화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.93, 302-314, January, 2021
DOI10.1016/j.jiec.2020.10.006  Export Citation
Kinetics and column adsorption study of diclofenac and heavy-metal ions removal by amino-functionalized lignin microspheres
Ana L. Popovic, Jelena D. Rusmirovic1, †, Zlate Velickovic2, Tihomir Kovacevic1, Aleksandar Jovanovic, Ilija Cvijetic3, and Aleksandar D. Marinkovic
  • Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade 11120, Serbia
  • 1Military Technical Institute, Ratka Resanovica 1, Belgrade 11000, Serbia
  • 2Military Academy, University of Defense, Generala Pavla Jurisic Sturma 33, Belgrade 11040, Serbia
  • 3Innovation Center of the Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, Belgrade 11000, Serbia
E-mail:
In-depth kinetic and column adsorption study for diclofenac, DCF, heavy-metal and oxyanions adsorption on highly effective amino-functionalized lignin-based microsphere adsorbent (A-LMS) is examined. The A-LMS was synthesized via inverse suspension copolymerization of industrial kraft lignin with the amino containing grafting-agent (polyethylene imine), and an epoxy chloropropane cross-linker. The batch adsorption results indicated process spontaneity and feasibility of a high removal capacity: DCF(151.13)>>Cd2+(74.84)>Cr(VI)(54.20)>As(V)(53.12)>Ni2+(49.42 mg g-1). The quantum chemical calculated interaction energies reveal stabilization of the A-LMS/DCF complex through the electrostatics and van der Waals interactions. The results from the pseudo-second order and Weber-Morris fitting indicate a fast removal rate; thus, column tests were undertaken. The single resistance mass transfer model, i.e. the mass transfer (kfa) and diffusion coefficient (Deff), shows pore diffusional transport as a rate limiting step. The fitting of the fixed bed column data with empirical models demonstrates the influences of flow rate and adsorbate inlet concentration on the breakthrough behavior. Pore surface diffusion modeling (PSDM) expresses mass transport under applied hydraulic loading rates, calculated breakthrough point adsorption capacities: Cd2+(58.1)>Cr(VI)(54.1)>As(V)(50.9)>>Ni2+(42.9 mg g-1)), without performing the experimentation on a full pilot-scale level, further confirms the high applicability of the A-LMS bio-based adsorbent.
Keywords:Interaction energy;Fixed-bed column;Ligno;-materials;Pharmaceutics removal;Theoretical calculation
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