상업용 유리프릿의 소결 공정을 이용한 내수성을 갖는 CsPbBr3/Glass 세라믹 복합체의 제작

문나은; 김성훈; Na-eun Mun; Sunghoon Kim

Korean Journal of Materials Research, Vol.31, No.1, 54-59, January, 2021

DOI10.3740/MRSK.2021.31.1.54 Export Citation

상업용 유리프릿의 소결 공정을 이용한 내수성을 갖는 CsPbBr3/Glass 세라믹 복합체의 제작

Simple Fabrication of Green Emission and Water-Resistant CsPbBr3 Encapsulation Using Commercial Glass Frits

문나은, 김성훈^†

동의대학교 공과대학 응용화학과

Na-eun Mun, and Sunghoon Kim^†

Department of Applied Chemistry and Food Science Technology, Dong-Eui University, Busan 47340, Republic of Korea

E-mail:

In this work, narrow-band green-emitting CsPbBr3 particles are embedded in commercialized glass composites by a facile dry process. By optimizing the method through sintering in glass frit (GF) composites including CsBr and PbBr2, used as precursors, the encapsulation of CsPbBr3 particles made them waterproof with green fluorescence. To improve the fluorescent properties by reducing aggregation of CsPbBr3, fumed silica (FS) is additionally used to help particles avoid bulking up in the glass matrix. The CsPbBr3 perovskite/glass composites are characterized using scanning electron microscopy (SEM) images and energy-dispersive X-ray spectroscopy (EDS) maps, which support the existence of CsPbBr3 particles in the glass matrix. The photoluminescence (PL) properties demonstrate that the emission spectrum peak, full width at half maximum (FWHM), and photoluminescence quantum yield (PLQY) values are 519 nm, 17 nm, and 17.7 %. We also confirm the water-resistant properties. To enhance water/moisture stability, the composite sample is put directly into water, with its PLQY monitored periodically under UV light.

Keywords:perovskite/ceramic composite;CsPbBr3;phosphor in glass;sintering process

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[1] Stranks SD, Snaith HJ, Nat. Nanotechnol., 10(5), 391 (2015)

[2] Green MA, Ho-Baillie A, Snaith HJ, Nat. Photonics, 8, 506 (2014)

[3] Jung HS, Park NG, Small, 11, 10 (2015)

[4] Li J, Xu L, Wang T, Song J, Chen J, Xue J, Dong Y, Cai B, Shan Q, Han B, Zeng H, Adv. Mater., 29 (2017)

[5] Zhang XL, Xu B, Zhang JB, Gao Y, Zheng YJ, Wang K, Sun XW, Adv. Funct. Mater., 26(25), 4595 (2016)

[6] Song JZ, Li JH, Li XM, Xu LM, Dong YH, Zeng HB, Adv. Mater., 27(44), 7162 (2015)

[7] Ramasamy P, Lim DH, Kim B, Lee SH, Lee MS, Lee JS, ChemComm., 52, 2067 (2016)

[8] Ding J, Du S, Zuo Z, Zhao Y, Cui H, Zhan X, J. Phys. Chem. C, 121, 4917 (2017)

[9] Cho MY, Kim S, Kim IS, Kim ES, Wang ZJ, Kim NY, Kim SW, Oh JM, Adv. Funct. Mater., 30, 190744 (2019)

[10] Song JZ, Li JH, Li XM, Xu LM, Dong YH, Zeng HB, Adv. Mater., 27(44), 7162 (2015)

[11] Shan Q, Li J, Song J, Zou Y, Xu L, Xue J, Dong Y, Huo C, Chen J, Han B, J. Mater. Chem. C, 5, 4565 (2017)

[12] Kulbak M, Gupta S, Kedem N, Levine I, Bendikov T, Hodes G, Cahen D, J. Phys. Chem. Lett., 7, 167 (2016)

[13] Kulbak M, Cahen D, Hodes G, J. Phys. Chem. Lett., 6, 2452 (2015)

[14] Yuan Y, Huang J, Accounts Chem. Res., 49, 286 (2016)

[15] Tai Q, You P, Sang H, Liu Z, Hu C, Chan HL, Yan F, Nat. Commun., 7, 1 (2016)

[16] Di X, Jiang J, Hu Z, Zhou L, Li P, Liu S, Xiang W, Liang X, Dyes Pigment., 146, 361 (2017)

[17] Wang HC, Lin SY, Tang AC, Singh BP, Tong HC, Chen CY, Lee YC, Tsai TL, Liu RS, Angew. Chem.-Int. Edit., 55, 7924 (2016)

[18] Sun C, Zhang Y, Ruan C, Yin CY, Wang XY, Wang YD, Yu WW, Adv. Mater., 28(45), 10088 (2016)

[19] Ai B, Liu C, Wang J, Xie J, Han JJ, Zhao XJ, J. Am. Ceram. Soc., 99(9), 2875 (2016)

[20] Xiang X, Lin H, Xu J, Cheng Y, Wang C, Zhang L, Wang Y, Chem. Eng. J., 378, 122255 (2019)

[21] Yuan S, Chen D, Li X, Zhong J, Xu X, ACS Appl. Mater. Interfaces, 10, 18918 (2018)

[22] Ye Y, Zhang W, Zhao Z, Wang J, Liu C, Deng Z, Zhao X, Han J, Adv. Opt. Mater., 7, 180166 (2019)

[23] Zhang R, Lin H, Yu Y, Chen D, Xu J, Wang Y, Laser Photonics Rev., 8, 158 (2014)

[24] Lee JS, Arunkumar P, Kim S, Lee IJ, Lee H, Im WB, Opt. Lett., 39, 762 (2014)

[25] Park JP, Lee TK,Kwak SK, Kim SW, Dyes Pigment., 144, 151 (2017)