화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.94, 361-367, February, 2021
DOI10.1016/j.jiec.2020.11.007  Export Citation
Chemoselective hydrogenation of α,β-unsaturated carbonyl compounds using a recyclable Ru catalyst embedded on a bisphosphine based POP
Sudakar Padmanaban1, 2, Yunho Lee2, and Sungho Yoon1, †
  • 1Department of Chemistry, Chung-Ang University, 84 Heukseok-ro, Heukseok-dong, Dongjak-gu, Seoul 06974, Republic of Korea
  • 2Department of Chemistry, Seoul National University, Seoul 08826, Republic of Korea
E-mail:
Selective hydrogenation of the carbonyl functional group of α,β-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240 h-1) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation.
Keywords:Heterogeneous catalysis;Ru catalysis;Green Chemistry;Chemoselective hydrogenation;α,β-Unsaturated carbonyl compounds;Allylic alcohol
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