ZnO nanoparticles-laden cellulose nanofibers-armored Pickering emulsions with improved UV protection and water resistance

Duho Lee; Daehwan Park; Kyounghee Shin; Hye Min Seo; Hyunsuk Lee; Yeongjin Choi; Jin Woong Kim

Journal of Industrial and Engineering Chemistry, Vol.96, 219-225, April, 2021

DOI10.1016/j.jiec.2021.01.018 Export Citation

ZnO nanoparticles-laden cellulose nanofibers-armored Pickering emulsions with improved UV protection and water resistance

Duho Lee, Daehwan Park, Kyounghee Shin, Hye Min Seo, Hyunsuk Lee¹, Yeongjin Choi¹, and Jin Woong Kim^†

School of Chemical Engineering, Sungkyunkwan University, Suwon 16419, Republic of Korea
¹Amorepacific R&D Center, Yongin 17074, Republic of Korea

E-mail:

This study introduces a new type of Pickering emulsion system with enhanced UV-blocking and water-resisting performance, in which hydrophobically modified ZnO composite cellulose nanofibers (HCNFZnO) were employed to form an oil-in-water (O/W) interface. For this, we first deposited ZnO nanoparticles (NPs) on CNFs by reducing the zinc precursor and subsequently grafted hexadecyl- trimethoxysilane on the ZnO NPs. We observed that the HCNFZnO favoured the formation of a fibrillary solid layer at the O/W interface, thus producing a structurally stable Pickering emulsion. The Pickering emulsion showed synergistic UV-blocking performance when prepared with a chemical UV filter in the oil phase. Interestingly, owing to the inter-fibrillary attraction of cellulose bodies, the HCNFZnO-armored Pickering emulsion drops adhere to each other, thus exhibiting significant resistance to repeated rinsing with water. These results highlight that our HCNFZnO enables the development of a UV-blocking emulsion system with excellent water resistance without the aid of conventional emulsifiers.

Keywords:Cellulose nanofibers;ZnO nanoparticle;Pickering emulsion;UV protection;Water resistance

[References]

Raffa P, Wever DAZ, Picchioni F, Broekhuis AA, Chem. Rev., 115(16), 8504 (2015)
Vitiello R, Rossano C, Russo KI, D’Errico G, Di SM, J. Surfactants Deterg., 23(1), 5 (2019)
Yang T, Choi SK, Lee YR, Cho Y, Kim JW, Polym. Chem., 7(20), 3471 (2016)
Abdala AA, Amin S, van Zanten JH, Khan SA, Langmuir, 31(13), 3944 (2015)
Kim DH, Kim JW, Oh SG, Kim J, Han SH, Chung DJ, Suh KD, Polymer, 48(13), 3817 (2007)
Honda S, Koga M, Tokita M, Yamamoto T, Tezuka Y, Polym. Chem., 6(22), 4167 (2015)
Anjali TG, Basavaraj MG, Langmuir, 35(1), 3 (2019)
Nam JB, Ryu JH, Kim JW, Chang IS, Suh KD, Polymer, 46(21), 8956 (2005)
Honda K, Sazuka Y, Iizuka K, Matsui S, Uchihashi T, Kureha T, Angew. Chem.-Int. Edit., 131, 7372 (2019)
Kim JW, Ko JY, Jun JB, Chang IS, Kang HH, Suh KD, Colloid Polym. Sci., 281(2), 157 (2003)
Li W, Suzuki T, Minami H, Angew. Chem.-Int. Edit., 57(31), 9936 (2018)
Lee JY, Choi KH, Hwang J, Sung M, Kim JE, Park BJ, et al., Chem. Commun., 56(45), 6031 (2020)
Goi Y, Fujisawa S, Saito T, Yamane K, Kuroda K, Isogai A, Langmuir, 35(33), 10920 (2019)
Seo M, Seo M, Choi SE, Shin K, Lee JB, Yang DY, et al., Carbohydr. Polym., 229, 115559 (2020)
Liu X, Qi X, Guan Y, He Y, Li S, Liu H, et al., Carbohydr. Polym., 224, 115202 (2019)
Kim DW, Shin J, Choi SQ, Carbohydr. Polym., 247, 116762 (2020)
Thomas B, Raj MC, Athira KB, Rubiyah MH, Joy J, Moores A, Drisko GL, Sanchez C, Chem. Rev., 118(24), 11575 (2018)
Mohammed N, Baidya A, Murugesan V, Kumar AA, Ganayee MA, Mohanty JS, et al., ACS Sustain. Chem. Eng., 4(11), 6167 (2016)
Lee YR, Park D, Choi SK, Kim M, Baek HS, Nam J, et al., ACS Appl. Mater. Interfaces, 9(36), 31095 (2017)
Bethke K, Palantoken S, Andrei V, Roβ M, Raghuwanshi VS, Kettemann F, et al, Adv. Funct. Mater., 28, 180040 (2018)
Li S, Huang JG, Adv. Mater., 28(6), 1143 (2016)
Alavi M, Nokhodchi A, Carbohydr. Polym., 227, 115349 (2020)
Limo MJ, Sola-Rabada A, Boix E, Thota V, Westcott ZC, Puddu V, Perry CC, Chem. Rev., 118(22), 11118 (2018)
Liao XQ, Liao QL, Zhang Z, Yan XQ, Liang QJ, Wang QY, Li MH, Zhang Y, Adv. Funct. Mater., 26(18), 3074 (2016)
Shifrina ZB, Matveeva VG, Bronstein LM, Chem. Rev., 120(2), 1350 (2020)
Shin K, Gong G, Cuadrado J, Jeon S, Seo M, Choi HS, et al., Chem. Eur. J., 23(18), 4292 (2017)
Awan F, Islam MS, Ma Y, Yang C, Shi Z, Berry RM, Tam KC, ACS Omega, 3(10), 12403 (2018)
Yeasmin S, Yeum JH, Yang SB, Carbohydr. Polym., 240, 116307 (2020)
Park YJ, Seo HM, Lee JY, Shin K, Kim JW, Adv. Mater. Interfaces, 7(15), 200052 (2020)
Guan Y, Yu HY, Abdalkarim SYH, Wang C, Tang F, Marek J, et al., Int. J. Biol. Macromol., 132, 51 (2019)
Goh EG, Xu X, McCormick PG, Scr. Mater., 78, 49 (2014)
Faure B, Salazar-Alvarez G, Ahniyaz A, Villaluenga I, Berriozabal G, De Miguel YR, Bergstrom L, Sci. Technol. Adv. Mater., 14(2), 023001 (2013)
Ghamsari MS, Alamdari S, Han W, Park HH, Inter. J. Nanomed., 12, 207 (2017)
Wang WH, Liang HT, Yang-Wang YT, Shih CJ, RSC Adv., 10(27), 15846 (2020)
Lee JH, Hong JY, An SY, Lee HJ, Kim SY, Lee JB, Kim JW, et al., J. Soc. Cosmet. Sci. Korea, 45(2), 199 (2019)

[Referenced By]

[1] Raffa P, Wever DAZ, Picchioni F, Broekhuis AA, Chem. Rev., 115(16), 8504 (2015)

[2] Vitiello R, Rossano C, Russo KI, D’Errico G, Di SM, J. Surfactants Deterg., 23(1), 5 (2019)

[3] Yang T, Choi SK, Lee YR, Cho Y, Kim JW, Polym. Chem., 7(20), 3471 (2016)

[4] Abdala AA, Amin S, van Zanten JH, Khan SA, Langmuir, 31(13), 3944 (2015)

[5] Kim DH, Kim JW, Oh SG, Kim J, Han SH, Chung DJ, Suh KD, Polymer, 48(13), 3817 (2007)

[6] Honda S, Koga M, Tokita M, Yamamoto T, Tezuka Y, Polym. Chem., 6(22), 4167 (2015)

[7] Anjali TG, Basavaraj MG, Langmuir, 35(1), 3 (2019)

[8] Nam JB, Ryu JH, Kim JW, Chang IS, Suh KD, Polymer, 46(21), 8956 (2005)

[9] Honda K, Sazuka Y, Iizuka K, Matsui S, Uchihashi T, Kureha T, Angew. Chem.-Int. Edit., 131, 7372 (2019)

[10] Kim JW, Ko JY, Jun JB, Chang IS, Kang HH, Suh KD, Colloid Polym. Sci., 281(2), 157 (2003)

[11] Li W, Suzuki T, Minami H, Angew. Chem.-Int. Edit., 57(31), 9936 (2018)

[12] Lee JY, Choi KH, Hwang J, Sung M, Kim JE, Park BJ, et al., Chem. Commun., 56(45), 6031 (2020)

[13] Goi Y, Fujisawa S, Saito T, Yamane K, Kuroda K, Isogai A, Langmuir, 35(33), 10920 (2019)

[14] Seo M, Seo M, Choi SE, Shin K, Lee JB, Yang DY, et al., Carbohydr. Polym., 229, 115559 (2020)

[15] Liu X, Qi X, Guan Y, He Y, Li S, Liu H, et al., Carbohydr. Polym., 224, 115202 (2019)

[16] Kim DW, Shin J, Choi SQ, Carbohydr. Polym., 247, 116762 (2020)

[17] Thomas B, Raj MC, Athira KB, Rubiyah MH, Joy J, Moores A, Drisko GL, Sanchez C, Chem. Rev., 118(24), 11575 (2018)

[18] Mohammed N, Baidya A, Murugesan V, Kumar AA, Ganayee MA, Mohanty JS, et al., ACS Sustain. Chem. Eng., 4(11), 6167 (2016)

[19] Lee YR, Park D, Choi SK, Kim M, Baek HS, Nam J, et al., ACS Appl. Mater. Interfaces, 9(36), 31095 (2017)

[20] Bethke K, Palantoken S, Andrei V, Roβ M, Raghuwanshi VS, Kettemann F, et al, Adv. Funct. Mater., 28, 180040 (2018)

[21] Li S, Huang JG, Adv. Mater., 28(6), 1143 (2016)

[22] Alavi M, Nokhodchi A, Carbohydr. Polym., 227, 115349 (2020)

[23] Limo MJ, Sola-Rabada A, Boix E, Thota V, Westcott ZC, Puddu V, Perry CC, Chem. Rev., 118(22), 11118 (2018)

[24] Liao XQ, Liao QL, Zhang Z, Yan XQ, Liang QJ, Wang QY, Li MH, Zhang Y, Adv. Funct. Mater., 26(18), 3074 (2016)

[25] Shifrina ZB, Matveeva VG, Bronstein LM, Chem. Rev., 120(2), 1350 (2020)

[26] Shin K, Gong G, Cuadrado J, Jeon S, Seo M, Choi HS, et al., Chem. Eur. J., 23(18), 4292 (2017)

[27] Awan F, Islam MS, Ma Y, Yang C, Shi Z, Berry RM, Tam KC, ACS Omega, 3(10), 12403 (2018)

[28] Yeasmin S, Yeum JH, Yang SB, Carbohydr. Polym., 240, 116307 (2020)

[29] Park YJ, Seo HM, Lee JY, Shin K, Kim JW, Adv. Mater. Interfaces, 7(15), 200052 (2020)

[30] Guan Y, Yu HY, Abdalkarim SYH, Wang C, Tang F, Marek J, et al., Int. J. Biol. Macromol., 132, 51 (2019)

[31] Goh EG, Xu X, McCormick PG, Scr. Mater., 78, 49 (2014)

[32] Faure B, Salazar-Alvarez G, Ahniyaz A, Villaluenga I, Berriozabal G, De Miguel YR, Bergstrom L, Sci. Technol. Adv. Mater., 14(2), 023001 (2013)

[33] Ghamsari MS, Alamdari S, Han W, Park HH, Inter. J. Nanomed., 12, 207 (2017)

[34] Wang WH, Liang HT, Yang-Wang YT, Shih CJ, RSC Adv., 10(27), 15846 (2020)

[35] Lee JH, Hong JY, An SY, Lee HJ, Kim SY, Lee JB, Kim JW, et al., J. Soc. Cosmet. Sci. Korea, 45(2), 199 (2019)