화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.96, 364-370, April, 2021
DOI10.1016/j.jiec.2021.01.048  Export Citation
10 μm-thick MoO3-coated TiO2 nanotubes as a volume expansion regulated binder-free anode for lithium ion batteries
Bumgi Heo, Jaeyun Ha, Yong-Tae Kim†, and Jinsub Choi†
  • Department of Chemistry and Chemical Engineering, Inha University, 22212, Incheon, South Korea
E-mail:,
In this study, 10μm-thick TiO2 nanotube arrays (TNAs) coated with a MoO3 layer were prepared by electrochemical oxidation on titanium foil followed by successive cyclic voltammetric deposition, aiming at the fabrication of a thick binder-free anode with high capacity and good cycling stability for lithium ion batteries (LIBs). Through the evaluation of the electrochemical performance of electrodes prepared under various conditions, the electrode obtained at a precursor concentration of 5 mM showed the best electrochemical performance, exhibiting high reversible capacity and enhanced cycling stability. With the structural advantage and intrinsic characteristics of TNAs, the large volume expansion of MoO3 is successfully accommodated, resulting in 97% retention at a rate of 5 C over 500 cycles and 91% retention even at a high rate of 25 C.
Keywords:Anodization;TiO2 nanotube;Cyclic voltammetry;MoO3;Lithium ion battery
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