The hydrogenation of naphthalene was performed with nickel catalysts (4 wt. % of Ni) supported on SBA-15 and Al-SBA-15 in order to evaluate the effect of the support's acidity on the activity and selectivity of the catalysts. The incorporation of aluminum into the SBA-15 support was performed during the hydrothermal synthesis of the material with the aim to reach the isomorphic substitution of Si4+ by Al3+ leading to the generation of Bronsted acid sites. Two different precursors (nickel nitrate and a Ni:EDTA complex) were used for the preparation of the catalysts on each support. Catalysts were characterized by nitrogen physisorption, powder X-ray diffraction, temperature programmed reduction, temperature programmed desorption of ammonia, scanning and high-resolution transmission electron microscopy. The Al-SBA-15 support was characterized by solid state Al-27 MAS-NMR. The results showed that the intrinsic activity of the catalysts (TOF) increased when the Al-SBA-15 support and the Ni:EDTA complex were used in the catalyst's preparation. The catalysts prepared using the Ni:EDTA complex showed high selectivity to decalins and higher proportion of trans-decalin in the products than the catalysts prepared with nickel nitrate, which was attributed to a higher dispersion of the metallic Ni species and the larger total amount of acid sites.