There is a growing interest in leaner burning internal combustion engines as an enabler for higher ther-modynamic efficiency. The extension of knock-limited compression ratio and the increase in specific heat ratio with lean combustion are key factors for boosting efficiency. Under lean burning conditions, there is emerging evidence that certain fuels exhibit unusual heat release characteristics. It has been reported that fuel/air mixtures undergo three-stage heat release or delayed high temperature heat release: starting with an initial low temperature heat release, similar to the one observed in two stage ignition, followed by an intermediate stage where thermal runaway is inhibited, and then advances to a relatively slow third stage of combustion. The focus of this study is to examine the conditions under which various fuels ex-hibit three stage ignition or delayed high temperature heat release. The auto-ignition of hydrocarbons/air mixtures is simulated in a closed adiabatic homogenous batch reactor where the charge is allowed to auto-ignite at constant volume vessel under predefined initial temperature and pressure. The simulations cover pressures of 10-60 bar, temperatures of 60 0 K-90 0 K, and fuel to air ratio from stoichiometry (equivalence ratio) of 0.3-1.0. Tangential stretching rate (TSR) and the computational singular perturba-tion Slow Importance Indices for temperature are used to identify important reactions contributing to the temperature growth rate at critical time instants of the auto-ignition process. Overall, three-stage ig-nition or delayed high temperature heat release is found to be present for most fuels under lean fuel/air mixtures, high pressures, and low temperature conditions. The radical termination reactions of H, OH, and HO2 during the high temperature heat release are leading factors for the distinct separation of heat release stages. (C) 2020 The Combustion Institute. Published by Elsevier Inc. All rights reserved.