화학공학소재연구정보센터
Industrial & Engineering Chemistry Research, Vol.59, No.42, 19030-19044, 2020
Fluid Dynamics Modeling of a Commercial Ebullated Bed Hydroprocessor
A new multiphase fluid dynamics model for a commercial ebullated bed hydroprocessor was developed. The impact of the gas-liquid distribution system is now explicitly included through new submodels for bubble size distribution and drag coefficients. The size distribution submodel is coupled with the existing gas-liquid separation submodel to better predict recycled gas and liquid flow rates. Either the mass of the catalyst inventory or recycle pump curve can be specified as inputs to converge the model; the former is not always well known during operation in which case the latter can be used after making a few assumptions. A sensitivity analysis was performed to study the impact of fresh treat gas velocity, catalyst mass, phase properties, and reactor internals on recycled gas and liquid flow rates, bubble size distribution, and bed liquid holdup. A 0.2 mm shift in bubble size distribution toward larger sizes was found to significantly increase bed liquid holdup, suggesting that distributor modification/redesign could help improve the capacity of the hydroprocessor.