Li2O-2B(2)O(3) (LBO) ionic conductor with high conductivity plays an important role in boosting the rate performance and cycling stability of Li4Ti5O12 (LTO) anode for lithium-ion batteries by preventing direct exposure of LTO to the electrolyte. Herein, the effect of LBO coating layer on lithium ion (Li+) storage performance is investigated in detail by adjusting the adding amount of LBO precursor dispersion. LTO coated with 2 wt% LBO achieves an optimum performance with a specific capacity of 172.9 mA h g(-1) at a current density of 0.1 A g(-1), an improved rate capability (specific capacity of 127.9 mA h g(-1) is maintained when the current density is 20 times than 0.1 A g(-1)) and a remarkable cycling stability (capacity retention of 94.2% after 4000 cycles at 2.0 A g(-1)). These LBO-LTO composites are competitive and promising candidates for electrochemical energy storage and other applications. (C) 2020 Elsevier Inc. All rights reserved.