Oxygen reduction reaction (ORR) catalyst is one of the most significant influential factors for the application of proton exchange membrane fuel cells. This work introduces a mass-producible high-performance PtZn alloy integrative structure ORR catalyst, synthesized with the atomically dispersive metal-organic framework precursors. This PtZn catalyst displays excellent catalytic activity with the onset reduction potential of 1.0 V-RHE@ 0.16 mA cm(-2) (Reversible hydrogen electrode; RHE) and the half-wave potential of 0.934 V-RHE for the ORR catalysis. The calculated specific activity and mass activity at 0.9 V are 9.44 A m(-2) and 544 A g(Pt)(-1), respectively, which are 5.62 times and 5.77 times as high as the commercial Pt/C. The mass activity is remarkably higher than the target put forward by the Department of Energy (DOE; 440 A g(Pt)(-1)). Furthermore, this PtZn catalyst also exhibits outstanding stability after the 10,000 potential cyclic degeneration test. The ORR current is much higher than Pt/C in the whole potential range not only before but also after the 10,000 potential cycles with identical Pt loading. This catalyst has a multifarious active-site catalytic structure with PtZn alloyed particles and atomically dispersive metal-N active sites on the N-doped graphited carbon matrix, exhibiting appealing ORR catalytic activity and sound stability for the application and scalable production of fuel cell catalysts. (C) 2020 Elsevier Inc. All rights reserved.