Controlling the morphology and structure of nanomaterials is of great importance for enhancing the electrochemical properties. In the paper, Mn3O4-Fe(3)O4@C hybrids with different architectures were synthesized by incubation of electrospun FeOx-containing carbon fiber (Fe-CNF) in KMnO4 solution followed by annealing. The presence of FeOx on the CNF plays a vital role in determining the morphology and structure of the final hybrids, and the Mn3O4-Fe3O4@C hybrids with half-tube, tube and oolite-filled fibers are formed conveniently by tuning Fe content in the carbon fiber precursor. The good conductivity of fiber and various redox states of Mn and Fe afford the facile charge transfer and excellent reversible redox properties, thus enhancing the capacitor performance. The oolite-filled Mn3O4-Fe3O4@C with tubular structure exhibited a high specific capacitance of 178 F g(-1) at a discharge rate of 1 A g(-1). This capacitor electrode has an excellent cyclic stability with 95% capacitance retention after 1000 cycles at 3 A g(-1). This work provides a very simple strategy to tune the unique nanostructures of metal oxide on Fe-CNF for high-performance supercapacitor application in the future. (C) 2020 Elsevier Inc. All rights reserved.