Manganese tungstate (MnWO4), zinc tungstate (ZnWO4), and copper tungstate (CuWO4) embedded biomass-derived carbon (MWO-C, ZWO-C, CWO-C) was synthesized by hydrothermal treatment and investigated as counter electrode (CE) catalysts to test electrochemical activity. Biomass-derived carbon was used as the shape controlling agent, which changed the morphology of MWO from spherical to spindle-like. Owing to the synergistic effect between tungsten-based bimetal oxides and biomass-derived carbon, the MWO-C, ZWO-C, and CWO-C catalysts exhibited enhanced electrochemical performance in dye-sensitized solar cells (DSSCs) system. The MWO-C, ZWO-C and CWO-C catalysts in DSSCs showed outstanding power conversion efficiency (PCE) of 7.33%, 7.61%, and 6.52%, respectively, as compared with 7.04% for Pt based devices. Biomass-derived carbon improves the catalytic properties of tungsten-based nanohybrids. The results showed that biomass-derived carbon-enhanced inorganic compound as CE catalysts are promising alternatives to Pt-based CE catalysts for energy conversion devices. (C) 2020 Elsevier Inc. All rights reserved.