Asphaltenes are a significant contributor to flow assurance problems related to crude oil production. Because of their polydispersity, model molecules such as coronene and violanthrone-79 (VO-79) have been used as mimics to represent the physiochemical properties of asphaltenes. This work aims to evaluate the emulsion-stabilization characteristics of fractionated asphaltenes and these two model molecules. Such evaluation is expected to better characterize the stabilizing mechanisms of asphaltenes on water-in-oil emulsions. The coalescence process of water-in-oil emulsion droplets is visualized using a microfluidic flow-focusing geometry. The rate of coalescence events is used as the parameter to assess emulsion stability. Interfacial tension (IFT) and oil/brine zeta potential are measured to help explain the differences in the rates of coalescence. VO-79 is found to be better at stabilizing emulsions as compared to coronene. Although VO-79 and asphaltenes have similar interfacial tension and oil/brine zeta potential values, the rate of coalescence differs significantly. This highlights the difficulty in using model molecules to mimic the transport dynamics of asphaltenes.