Journal of Vacuum Science & Technology A, Vol.16, No.4, 2240-2244, 1998
Role of the bias voltage during the deposition of thin tin oxide films by plasma assisted chemical vapor deposition
Nonstoichiometric thin tin oxide films have been deposited from an Ar-tetramethyltin-O-2 mixture in an rf glow discharge diode reactor at low pressure (15 Pa) and at low temperature (25-100 degrees C). These films are amorphous and present a high transmittance (95%) in the visible region. The conductivity of the films have been increased considerably (10(-2) to 10(2) Omega(-1) cm(-1)) in a triode system (substrate electrode biased by another rf generator), for treatment times as short as 10 min with a deposition rate of 30 nm/min. This increase of the conductivity leads to a decrease of the gap energy from 3.5 to 2.5 eV accompanied with a slight decrease of the transmittance (from 95% to 89% +/- 2%) and of the grain size (95 to 43 nm). The tin oxide-substrate interface analyzed by Rutherford backscattering has shown to be an abrupt one.