In the present work, we report synthesis of Cs2SnI6 double perovskite films by direct spray casting of precursor containing CsI and SnI2 dissolutions in DMF and the fabrication of solar cells using these films as absorber material. The films were prepared by varying the CsI: SnI2 molar ratio in the precursor, 2:1, 1:1, 1:2, 1:3 and 1:4. X-ray diffraction and Raman spectral analysis showed the formation of Cs2SnI6 films with cubic structure when the precursor solution contained excess fin iodide. The optical band gap value of the films was similar to 1.2-1.3 eV and the films were photoconductive. The stability studies established that the perovskite films were stable under ambient exposure. Further, we fabricated all-inorganic photovoltaic structures Glass/FTO/CdS/Cs2SnI6/C/Ag, using Cs2SnI6 films formed at different conditions as absorber layer. Post thermal annealing of the PV devices at 150 degrees C showed the highest V-oc = 0.86 V for this material. Thus, our results have demonstrated that spray deposition is a reproducible method to synthesize stable cesium fin iodide perovskite for applications in all inorganic p-n junction solar cells and other optoelectronic devices.