화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.97, 239-249, May, 2021
Carbon Nanotube.Manganese oxide nanorods hybrid composites for high-performance supercapacitor materials
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In the present work, multiwall carbon nanotubes (CNTs) were used as a reducing agent for the preparation of CNT-MnO2 nanocomposites by varying the amount of potassium permanganate (KMnO4). The chemical compositions of the as-synthesized materials were analyzed using X-ray diffraction, Fourier-transform infrared spectroscopy, and X-ray photoelectron spectroscopy, which showed the formation of MnO2 in the CNT-MnO2 nanocomposites. The electrochemical properties of the CNT-MnO2 nanocomposites were thoroughly investigated through cyclic voltammetry, charge.discharge, and impedance studies. The CNT-MnO2-25 nanocomposites appeared with the highest specific capacitance of 674 F g-1 at a current density of 2 A g-1; they also displayed an excellent capacitance retention of ~110% even after the completion of 5000 continuous charge.discharge cycles at 10 A g-1.
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