화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.97, 523-538, May, 2021
DOI10.1016/j.jiec.2021.03.016  Export Citation
Corrosion inhibition performance and computational studies of pyridine and pyran derivatives for API X-65 steel in 6 M H2SO4
Kurls E. Anwer, Ahmed A. Farag1, †, Eslam A. Mohamed1, †, Eman M. Azmy2, and Galal H. Sayed
  • Chemistry Department, Faculty of Science, Ain Shams University, Abbassia 11566, Cairo, Egypt
  • 1Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo, Egypt
  • 2Chemistry Department, Faculty for women, Ain Shams University, Heliopolis, Cairo, Egypt
E-mail:,
The present investigation aims to synthesize and explore the influence of pyridine and pyran derivatives on the API X-65 steel corrosion in a 6 M H2SO4 solution. The compound was examined at different concentrations to optimized the best concentration for the corrosion inhibition effect, weight loss measurements, potentiodynamic polarization measurement (PDP), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and theoretical methods were used to evaluating the inhibition efficiency. The obtained adsorption data achieved the model of Langmuir isotherm. The pyridine derivatives showed higher inhibition than pyran derivatives. The PDP tests proposed that pyridine and pyran derivatives are mixed-type inhibitors. The EIS parameters demonstrate that the double-layer capacitance (Cdl) decreases with the increase of inhibitor concentration, which implies a reduces dielectric constant. It was observed from experimental data that the inhibition efficiency reached 92.7%, 89.1, 94.7, and 85.2% for concentration 2.66 x 10-3M of I, II, III and IV, respectively indicating the inhibition order is III > I > II > IV. The parameters derived from the theoretical quantum chemical calculations were found adequately correlated with the obtained experimental results.
Keywords:Carbon steel;Pyridine;Pyran;Acid corrosion;SEM;Theoretical study;Molecular dynamics simulations
  1. Bentiss F, Lagrenee M, Traisnel M, Hornez JC, Corrosion Sci., 41, 789 (1999)
  2. Konno Y, Farag AA, Tsuji E, Aoki Y, Habazaki H, J. Electrochem. Soc. (2016).
  3. Ahamad I, Prasad R, Quraishi MA, Corrosion Sci., 52, 933 (2010)
  4. Farag AA, Ismail AS, Migahed MA, Egypt. J. Pet. (2018).
  5. Popova A, Sokolova E, Raicheva S, Christov M, Corrosion Sci., 45, 33 (2003)
  6. Abd El-Hafez GM, Badawy WA, Electrochim. Acta, 108, 860 (2013)
  7. Bouanis M, Tourabi M, Nyassi A, Zarrouk A, Jama C, Bentiss F, Appl. Surf. Sci., 389, 952 (2016)
  8. Farag AA, Corros. Rev., 38, 67 (2020)
  9. Mohamed HA, Farag AA, Badran BM, J. Appl. Polym. Sci., 117(3), 1270 (2010)
  10. Mohamed BMBHA, Farag AA, Eurasian Chem., 10, 67 (2008)
  11. Lgaz H, Bhat KS, Salghi R, Shubhalaxmi, Jodeh S, Algarra M, Hammouti B, Ali IH, Essamri A, J. Mol. Liq., 238, 71 (2017)
  12. Fekry AM, Mohamed RR, Electrochim. Acta, 55(6), 1933 (2010)
  13. Zarrouk A, Zarrok H, Ramli Y, Bouachrine M, Hammouti B, Sahibed-dine A, Bentiss F, J. Mol. Liq., 222, 239 (2016)
  14. Luo X, Pan X, Yuan S, Du S, Zhang C, Liu Y, Corrosion Sci., 125, 139 (2017)
  15. Morad MS, Corrosion Sci., 50, 436 (2008)
  16. Zhang G, Zhang Y, Yan J, Chen R, Wang S, Ma Y, Wang R, J. Org. Chem., 77, 878 (2012)
  17. El Hezzat M, Assouag M, Zarrok H, Benzekri Z, El Assyry A, Boukhris S, Souizi A, Galai M, Touir R, Ebn Touhami M, Oudda H, Zarrouk A, Der Pharma Chem, 7, 77 (2015)
  18. Khattabi M, Benhiba F, Tabti S, Djedouani A, El Assyry A, Touzani R, Warad I, Oudda H, Zarrouk A, J. Mol. Struct., 1196, 231 (2019)
  19. Yadav DK, Quraishi MA, Ind. Eng. Chem. Res., 51(24), 8194 (2012)
  20. Dohare P, Ansari KR, Quraishi MA, Obot IB, J. Ind. Eng. Chem., 52, 197 (2017)
  21. Singh A, Ansari KR, Quraishi MA, Lgaz H, Lin Y, J. Alloy. Compd., 762, 347 (2018)
  22. Sastri VS, Perumareddi JR, Corrosion, 53, 617 (1997)
  23. Ismail AS, Farag AA, Surf. Interfaces, 19, 100483 (2020)
  24. Ahmed MAM, Farag A, Ismail AS, J. Bio- Tribo-Corros, 6, 16 (2020)
  25. Farag AA, Migahed MA, Badr EA, J. Bio- Tribo-Corros., 5, 53 (2019)
  26. Nabah R, Benhiba F, Ramli Y, Ouakki M, Cherkaoui M, Oudda H, Touir R, Warad I, Zarrouk A, Anal. Bioanal. Electrochem., 10, 1375 (2018)
  27. Frisch M, et al., gaussian 09, Revision d. 01, Gaussian, Inc., Wallingford CT, 2009.
  28. Ramazani A, Sheikhi M, Yahyaei H, Chem. Methodol., 1, 28 (2017)
  29. Becke AD, Phys. Rev. A, 38, 3098 (1988)
  30. Lee C, Yang W, Parr RG, Phys. Rev., 37, 785 (1988)
  31. Becke AD, J. Chem. Phys., 98, 5648 (1993)
  32. Frisch MJ, et al., Gaussian, Inc. Wallingford, CT, (2009).
  33. Rbaa M, Benhiba F, Obot IB, Oudda H, Warad I, Lakhrissi B, Zarrouk A, J. Mol. Liq., 276, 120 (2019)
  34. Satoh S, Fujimoto H, Kobayashi H, J. Phys. Chem., 10, 4846 (2006)
  35. Zhang Z, Tian N, Zhang L, Wu L, Corrosion Sci., 98, 438 (2015)
  36. Qiang Y, Zhang S, Yan S, Zou X, Chen S, Corrosion Sci., 126, 295 (2017)
  37. Benbouguerra K, Chafaa S, Chafai N, Mehri M, Moumeni O, Hellal A, J. Mol. Struct., 1157, 165 (2018)
  38. Wang X, Yang H, Wang F, Corrosion Sci., 53, 113 (2011)
  39. Meresht ES, Farahani TS, Neshati J, Corrosion Sci., 54, 36 (2012)
  40. Farag AA, Corros. Rev., 36, 575 (2018)
  41. Farag AA, Ali TA, J. Ind. Eng. Chem., 21, 627 (2015)
  42. Solomon MM, Umoren SA, J. Colloid Interface Sci., 462, 29 (2016)
  43. Haque J, Ansari KR, Srivastava V, Quraishi MA, Obot IB, J. Ind. Eng. Chem., 49, 176 (2017)
  44. Ahmed MAM, Farag A, Ismail AS, J. Mol. Liq., 211, 915 (2015)
  45. Farag AA, Badr EA, Corros. Rev., 38, 151 (2020)
  46. Rassouli L, Naderi R, Mahdavain M, J. Ind. Eng. Chem., 66, 221 (2018)
  47. Huang H, Wang Z, Gong Y, Gao F, Luo Z, Zhang S, Li H, Corrosion Sci., 123, 339 (2017)
  48. Tan BC, Zhang ST, Liu HY, Guo YW, Qiang YJ, Li WP, Guo L, Xu CL, Chen SJ, J. Colloid Interface Sci., 538, 519 (2019)
  49. Mazumder MAJ, Al-Muallem HA, Faiz M, Ali SA, Corrosion Sci., 87, 187 (2014)
  50. Ralkhal S, Shahrabi T, Ramezanzadeh B, Bahlakeh G, Appl. Surf. Sci., 464, 178 (2019)
  51. Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 292, 111387 (2019)
  52. Tan B, Zhang S, Qiang Y, Li W, Li H, Feng L, Guo L, Xu C, Chen S, Zhang G, J. Mol. Liq., 298, 111975 (2020)
  53. Tan B, Zhang S, Qiang Y, Li W, Liu H, Xu C, Chen S, J. Mol. Liq., 286, 110891 (2019)
  54. Farag AA, Noor El-Din MR, Corrosion Sci., 64, 174 (2012)
  55. Migahed MA, Farag AA, Elsaed SM, Kamal R, El-Bary EA, Chem.Eng. Commun., 199, 1335 (2012)
  56. Migahed MA, Farag AA, Elsaed SM, Kamal R, Mostfa M, El-Bary HA, Mater. Chem. Phys. (2011).
  57. Mishra A, Verma C, Lgaz H, Srivastava V, Quraishi MA, Ebenso EE, J. Mol. Liq., 251, 317 (2018)
  58. Tan B, Zhang S, Qiang Y, Feng L, Liao C, Xu Y, Chen S, J. Mol. Liq., 248, 902 (2017)
  59. Tan BC, Zhang ST, Qiang YJ, Guo L, Feng L, Liao CH, Xu Y, Chen SJ, J. Colloid Interface Sci., 526, 268 (2018)
  60. Tan B, Zhang S, Li W, Zuo X, Qiang Y, Xu L, Hao J, Chen S, J. Ind. Eng. Chem., 77, 449 (2019)
  61. Farag AA, Hegazy MA, Corrosion Sci., 74, 168 (2013)
  62. Verma C, Singh A, Pallikonda G, Chakravarty M, Quraishi MA, Bahadur I, Ebenso EE, J. Mol. Liq., 29, 306 (2015)
  63. Yıldız R, Corrosion Sci., 90, 544 (2015)
  64. Obot IB, Obi-Egbedi NO, Corrosion Sci., 52, 198 (2010)
  65. Tian H, Li W, Cao K, Hou B, Corrosion Sci., 73, 281 (2013)
  66. Zhang K, Xu B, Yang W, Yin X, Liu Y, Chen Y, Corrosion Sci., 90, 284 (2015)
  67. Xia G, Jiang X, Zhou L, Liao Y, Duan M, Wang H, Pu Q, Zhou J, Corrosion Sci., 94, 224 (2015)
  68. Daoud D, Douadi T, Hamani H, Chafaa S, Al-Noaimi M, Daoud MAND, Douadi T, Hamani H, Chafaa S, Corrosion Sci., 94, 21 (2015)
  69. Torres VV, Rayol VA, Magalhaes M, Viana GM, Aguiar LCS, Machado SP, Orofino H, D’Elia E, Corrosion Sci., 79, 108 (2014)
  70. Baskar R, Kesavan D, Gopiraman M, Subramanian K, Prog. Org. Coat., 77, 836 (2014)
  71. Yang W, Mortier WJ, J. Am. Chem. Soc., 108, 5708 (1986)
  72. Xu B, YAng W, Liu Y, Yin X, Gong W, Chen Y, Corrosion Sci., 78, 260 (2014)
  73. Caleyo F, Velazquez JC, Valor A, Hallen JM, Corrosion Sci., 51, 1925 (2009)
  74. Matos JB, Pereira LP, Agostinho SML, Barcia OE, Cordeiro GGO, D'Elia E, J. Electroanal. Chem., 570(1), 91 (2004)
  75. Li HFX, Deng S, Corrosion Sci., 53, 302 (2011)
  76. Aljourani J, Raeissi K, Golozar MA, Corrosion Sci., 51, 1836 (2009)
  77. Murmu M, Saha SK, Murmu NC, Banerjee P, Corrosion Sci., 146, 134 (2019)
  78. Zhang QB, Hua YX, Electrochim. Acta, 54(6), 1881 (2009)
  79. El-Maksouda SAA, Fouda AS, Mater. Chem. Phys., 93(1), 84 (2005)
  80. Ogretir C, Mihci B, Bereket G, J. Mol. Struct. Theochem., 488, 223 (1999)
  81. Kosari A, Moayed MH, Davoodi A, Parvizi R, Momeni M, Eshghi H, Moradi H, Corrosion Sci., 78, 138 (2014)
  82. Ansari K, Quraishi M, Singh A, Measurement, 76, 136 (2015)
  83. Lashkari M, Arshadi M, Chem. Phys., 299, 131 (2004)
  84. Sudheer, Quraishi MA, Ind. Eng. Chem. Res., 53(8), 2851 (2014)
  85. Yıldız R, Doner A, Dogan T, Dehri I, Corrosion Sci., 82, 125 (2014)
  86. Morad M, El-Dean AK, Corrosion Sci., 48, 3398 (2006)
  87. Verma C, Quraishi M, Olasunkanmi L, Ebenso EE, RSC Adv., 55, 85417 (2015)
  88. Eldesoky AM, Attia AM, Ahmed OE, Abo-Elsoud MA, J. Mater. Sci. Chem. Eng., 7, 71 (2019)
  89. Alaoui K, Touir R, Galai M, Serrar H, Ouakki M, Kaya S, Tuzun B, Boukhris S, Touhami ME, El Kacimi Y, J. Bio- Tribo-Corros., 4, 37 (2018)
  90. Ameer MA, Fekry AM, Int. J. Hydrog. Energy, 35(20), 11387 (2010)