화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.98, 180-188, June, 2021
DOI10.1016/j.jiec.2021.04.004  Export Citation
Hierarchical Lamellar Aluminophosphate Inorganic Materials for Medium Density Fiberboard with Good Fire Performance
Zhenzeng Wu1, 2, Tingjie Chen3, †, John Tosin Aladejana2, Yves Kouomo Guelifack2, Dehong Li2, Xinjun Hou2, Xiaodong(Alice) Wang4, Min Niu2, †, and Yongqun Xie2, †
  • 1The College of Ecology and Resource Engineering, Wuyi University, No. 16, Wuyi Avenue, Wuyishan, Fujian 354300, PR China
  • 2The College of Material Engineering, Fujian Agriculture and Forestry University, 15 Shangxiadian Road, Fuzhou, Fujian 350002, PR China
  • 3The College of Materials Science and Engineering, Fujian University of Technology, Fuzhou, Fujian 350002, PR China
  • 4The Department of Wood and Forest Sciences, Laval University, Quebec G1 V 0A6, Canada
E-mail:, ,
Fire safety issues have attracted much attention since they cause enormous loss of lives and properties. In this study, the sustainable aluminophosphate (AP) adhesive is developed as a fire retardant for improving the fire performance of medium-density fiberboard (MDF). The properties of AP adhesive and AP-based MDF were evaluated based on a scanning electron microscope, thermogravimetric analysis, X-ray diffraction, X-ray photoelectron spectroscopy, and cone calorimetry. The thermostability and fire performance of MDF are significantly improved by the deposition of the AP inorganic layer on the wood fibers surface, which could protect wood fibers from further oxidation and take away part of the heat. Compared to control sample (UF sample), the pkHRR (151.7 kW m-2), THR (66.0 MJ m-2), TTI (21 s), and mean EHC (14.6 MJ kg-1) of AP-based MDF was reduced by 52.7%, 39.0%, 41.7%, and 32.8%, respectively. Also, the existence of the AP inorganic layer is beneficial to netting the solid phase and volatile flammable components in char residue of MDF, resulting in large mass loss rate, off-gases (CO and CO2) release and smoke suppression properties. Therefore, AP could improve the fire performance of MDF.
Keywords:eco-friendly adhesive;flame retardant;smoke suppression;inorganic insulation layer;catalytic charring
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