화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.98, 200-210, June, 2021
DOI10.1016/j.jiec.2021.04.001  Export Citation
The dye adsorption and antibacterial properties of composite polyacrylamide cryogels modified with ZnO
Murat _Inal†, Nuran Erduran1, and Murat Gokgoz2
  • Bioengineering Department, Engineering and Architecture Faculty, Kırıkkale University, Yahşihan 71450, Turkey
  • 1Chemistry Department, Science and Art Faculty, Kırıkkale University, Yahsihan 71450, Turkey
  • 2Department of Nutrition and Dietetics, Faculty of Health Sciences, Kırıkkale University, Yahsihan 71450, Turkey
E-mail:
The present study aimed to modify the surface of polyacrylamide cryogels (PAC) with ZnO nanorods (ZNR) to provide them with antibacterial properties. The synthesized ZNR-modified composite PAC (ZMC) characterized by AAS, FTIR, SEM, XRD, XPS, BET surface analysis and TGA studies. A study of the adsorption of Orange G (OG) and antibacterial effect was performed on the synthesized ZMC. The highest adsorption capacity was determined to be at a dye concentration of 142.79 mg/g at 400 ppm, and a pH of 2. From the data obtained, it was found that adsorption fitted the pseudo-second-order kinetic model and Freundlich isotherm. Modified cryogels could be desorbed in a very short time . such as 30 min . and reused approximately twenty times with 80% efficiency. While ZMC cryogels did not show antibacterial activity in the dark, inhibition percentages were determined as 99.79 ±3.94% and 99.81 ±1.76%, at 1.78 mg/mL cryogel application, MIC90 values were determined as 1.589 ± 0.063 and 0.660 ± 0.028 mg/ mL for Escherichia coli, and Staphylococcus aureus, respectively under visible light. The results showed that the composite cryogels obtained had a very high potential to be applied both in the removal of dyes from wastewater and in the purification of microorganism-contaminated water.
Keywords:Zinc oxide nanorod;Polyacrylamide;Cryogel;Adsorption;Orange G
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