The nano-magnetite-loaded 2-mercaptobenzoxazole as an adsorbent for the selective removal of the Pb2+, Ni2+ and Cd2+ ions from aqueous solutions

Maryam Ariannezhad; Davood Habibi; Somayyeh Heydari; Vahideh Khorramabadi

Korean Journal of Chemical Engineering, Vol.38, No.7, 1510-1521, July, 2021

DOI10.1007/s11814-021-0792-6 Export Citation

The nano-magnetite-loaded 2-mercaptobenzoxazole as an adsorbent for the selective removal of the Pb2+, Ni2+ and Cd2+ ions from aqueous solutions

Maryam Ariannezhad^{1, †}, Davood Habibi¹, Somayyeh Heydari^{1, 2}, and Vahideh Khorramabadi¹

¹Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683, Iran
²Department of Research and Development of the Faran Shimi Pharmaceutical Company, Tuyserkan, Iran

E-mail:

The present research focuses on the adsorption efficiency of nano-magnetite loaded 2-mercapto- benzoxazole as an adsorbent (Fe3O4@SiO2@CPTMS@MBOL) for Pb+2, Ni+2 and Cd+2 removal from the contaminated water by the technique of adsorption. The influence of pH, contact time, adsorbent dosage and temperature in 50 ppm concentration of each ion solutions on the sensitivity of the removal procedure was examined. By ICP test the adsorption data were fixed to linearize the adsorption isotherms of the Langmuir and Freundlich equations. This efficient adsorbent showed significant results for metal ion removal from water by formation of complex with adsorbent. From the Langmuir isotherm, the maximum adsorption capacities of nano magnetic adsorbent towards Pb2+, Ni2+ and Cd2+ ions were 238.4, 203.2 and 22.37mgg-1.

Keywords:Adsorption;2-Mercaptobenzoxazole;Adsorption Isotherms;Solution Ions;Nano Magnetic

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[2] Muthusaravanan S, Sivarajasekar N, Vivek JS, Paramasivan T, Naushad M, Prakashmaran J, Gayathri V, Al-Duaij OK, Environ. Chem. Lett., 16, 1339 (2018)

[3] Rambabu K, Thanigaivelan A, Bharath G, Sivarajasekar N, Banat F, Show PL, Chemosphere, 268, 128809 (2021)

[4] Janani K, Sivarajasekar N, Muthusaravanan S, Ram K, Prakashmaran J, Sivamani S, Dhakal N, Shahnaz T, Selvaraju N, Bioresour. Technol., 7, 100265 (2019)

[5] Sharavanan VJ, Sivaramakrishnan M, Sivarajasekar N, et al., Environ. Chem. Lett., 18, 325 (2020)

[6] Muthusaravanan S, et al., Green Materials for Wastewater Treatment, 38, 191 (2020).

[7] Jun BM, Her N, Park CM, Yoo Y, Environ. Sci. Water Res. Technol., 6, 173 (2020)

[8] Bobadilla MC, Lorza RL, Gomez FS, Garcia RE, Water, 12, 1320 (2020)

[9] Devatha CP, Shivani S, J. Environ. Manage., 258, 110038 (2020)

[10] Azimi A, Azari A, Rezakazemi M, Ansarpour M, ChemBio-Eng Rev., 4, 37 (2017)

[11] Rahman MM, Asaduzzaman M, Naidu R, J. Hazard. Mater., 262, 1056 (2013)

[12] Anjum M, Miandad R, Waqa M, Gehany F, Barakat MA, Arab. J. Chem, 12, 4897 (2019)

[13] Lin LC, Li JK, Juang RS, Desalination, 225(1-3), 249 (2008)

[14] Fan HL, Zhou SF, Jiao WZ, Qi GS, Liu YZ, Carbohydr. Polym., 174, 1192 (2017)

[15] Bessbousse H, Rhlalou T, Verchere JF, Lebrun L, J. Membr. Sci., 307(2), 249 (2008)

[16] Benito Y, Ruiz ML, Desalination, 142(3), 229 (2002)

[17] Zhao F, Tang WZ, Zhao D, Meng Y, Yin D, Sillanpaa M, J. Water Process Eng., 4, 47 (2014)

[18] Kobya M, Demirbas E, Senturk E, Ince M, Bioresour. Technol., 96(13), 1518 (2005)

[19] Panneerselvam P, Bala V, Thinakaran N, Baskaralingam P, Palanichamy M, Sivanesan S, E- J. Chem., 6, 729 (2009)

[20] Jiang MQ, Jin XY, Lu XQ, Chen ZL, Desalination, 252(1-3), 33 (2010)

[21] Ambashta RD, Sillanpaa M, J. Hazard. Mater., 180(1-3), 38 (2010)

[22] Sharma YC, Srivastava V, Singh CK, Kaul SN, Weng CH, Environ. Technol., 30, 583 (2009)

[23] White BR, Stackhouse BT, Holcombe JA, J. Hazard. Mater., 161(2-3), 848 (2009)

[24] Sharma YC, Srivastava V, J. Chem. Eng. Data, 55(3), 1441 (2010)

[25] Karami H, Chem. Eng. J., 219, 209 (2013)

[26] Badruddoza AZM, Shawon ZBZ, Tay WJD, Hidajat K, Uddin MS, Carbohydr. Polym., 91, 322 (2013)

[27] Ariannezhad M, Habibi D, Heydari S, Russ. J. Org. Chem., 55, 1591 (2019)

[28] Hawkes SJ, J. Chem. Educ., 73, 516 (1996)

[29] Watanabe H, Seto JE, Bull. Chem. Soc. Jpn., 59, 2683 (1986)

[30] Pirarath R, Shivashanmugam P, Syed A, Elgorban AM, AnandanAnandan S, Ashokkumar M, Front Environ. Sci. Eng., 15, 1 (2021)

[31] Boparai HK, Joseph M, O'Carroll DM, J. Hazard. Mater., 186(1), 458 (2011)

[32] Madrakian T, Afkhami A, Ahmadi M, Chemosphere, 90, 542 (2013)

[33] Lian N, Chang X, Zheng H, Wang S, Cui Y, Zhai Y, Microchim. Acta, 151, 81 (2005)

[34] Mohammadi S, Afzali D, Pourtalebi D, Open Chem., 8, 662 (2010)

[35] Liu JY, Hu CW, Huang QG, Bioresour. Technol., 271, 487 (2019)

[36] Cui Y, Chang X, Zhai Y, Zhu ZH, Lian N, Microchem. J., 83, 35 (2006)

[37] Ozer A, J. Hazard. Mater., 141(3), 753 (2007)

[38] Heidari A, Younesi H, Mehraban Z, Chem. Eng. J., 153(1-3), 70 (2009)

[39] Huang C, Hu B, Spectroc. Acta Pt. B-Atom. Spectr., 63, 437 (2008)