화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.99, 214-223, July, 2021
DOI10.1016/j.jiec.2021.04.031  Export Citation
A sustainable way for surface functionalisation of PET nonwoven with novel chitosan-cinnamaldehyde cross-linked nanoparticles
Rahul R. Gadkari, Ashutosh Gupta, Uddesh Teke, Atul Awadhiya, Mohammad Shahadat1, Wazed Ali†, Apurba Das, and Ramasamy Alagirusamy
  • Department of Textile & Fibre Engineering, Indian Institute of Technology Delhi, New Delhi, 110016, India
  • 1School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800, Malaysia
E-mail:
In this study, a novel eco-friendly chitosan-cinnamaldehyde cross-linked nanoparticles (CSN) were synthesised via a green route and deposited, in alternating combination with sodium tripolyphosphate (TPP), over polyester (PET) nonwoven fabric using layer-by-layer (L-B-L) coating technique. The successful deposition of a nano-level coating (upto 684.7 nm) of 10.5 bi-layers of CSN and TPP, i.e. (CSN/ TPP)10.5, with CSN at the top, was achieved at individual fibre surface as confirmed via scanning electron microscopy. Fabric coated with (CSN/TPP)10.5 showed remarkable antibacterial activity against both the Gram-positive (Staphylococcus aureus) and Gram-negative (Escherichia coli) bacteria, even with a low concentration of the nanoparticles (0.1 w/v). Moreover, the coating material possesses very low toxicity as revealed by the cytotoxicity test. The developed fabric could also adsorb metal ions like Pb2+, Cu2+, Fe3+, Ni2+, Zr4+ and Cd2+, etc. from water. The coating was found to be stable in alkaline and neutral pH environments. The slight reduction in the pore dimensions, air permeability and tensile strength of fabric after coating were insignificant with respect to its potential applications in developing health care products, medical and health care textiles and dry or wet purification media.
Keywords:Chitosan;Cinnamaldehyde;Nanoparticles;Layer-by-layer coating;Antibacterial;Heavy metal adsorption
  1. Joshi M, Ali SW, Purwar R, Rajendran S, Indian J. Fibre Text. Res., 34(3), 295 (2009)
  2. Babu KM, Ravindra KB, J. Text. Inst., 106(7), 706 (2015)
  3. Gomes AP, Mano JF, Queiroz JA, Gouveia IC, Polym. Adv. Technol., 24(11), 1005 (2013)
  4. Gadkari RR, Ali SW, Das A, Alagirusamy R, Hussain CM, Handbook of Nanomaterials for Manufacturing Applications, Elsevier, pp.297, 2020.
  5. Purwar R, Islam S, Butola B, The Impact and Prospects of Green Chemistry for Textile Technology, Elsevier, pp.281, 2018.
  6. Joshi M, Ali SW, Rajendran S, J. Appl. Polym. Sci., 106(2), 793 (2007)
  7. Ibrahim NA, El-Zairy EMR, Eid BM, J. Text. Inst., 108(8), 1406 (2017)
  8. Leon-Silva S, Fernandez-Luqueno F, Lopez-Valdez F, Water Air Soil Pollut., 227(9) (2016)
  9. Perinelli DR, Fagioli L, Campana R, Lam JKW, Baffone W, Palmieri GF, Casettari L, Bonacucina G, Eur. J. Pharm. Sci., 117, 8 (2018)
  10. Ali SW, Rajendran S, Joshi M, Carbohydr. Polym., 83(2), 438 (2011)
  11. Sheikh J, Bramhecha I, Int. J. Biol. Macromol., 118, 896 (2018)
  12. Giachet FT, Periolatto M, Ramirez DOS, Carletto RA, Varesano A, Vineis C, Bongiovanni R, J. Ind. Text., 48(8), 1384 (2019)
  13. Yin X, Weng P, Han L, Liu J, Tan Y, Chen D, Zhou Y, Li S, Wang L, Wang H, Cellulose, 25(4), 2721 (2018)
  14. Benltoufa S, Miled W, Trad M, Slama RB, Fayala F, Carbohydr. Polym., 227 (2020)
  15. Aubert-Viard F, Mogrovejo-Valdivia A, Tabary N, Maton M, Chai F, Neut C, Martel B, Blanchemain N, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 100, 554 (2019)
  16. Shahid-ul I, Butola BS, Int. J. Biol. Macromol., 905 (2019).
  17. Gadkari R, et al., Derivatives, Composites and Applications, John Wiley & Sons, Inc., Hoboken, NJ, USA, pp.431, 2017.
  18. Kim IY, Seo SJ, Moon HS, Yoo MK, Park IY, Kim BC, Cho CS, Biotechnol. Adv., 26(1), 1 (2008)
  19. Costa EM, Silva S, Vicente S, Neto C, Castro PM, Veiga M, Madureira P, Tavaria F, Pintado MM, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 79, 221 (2017)
  20. Raafat D, Sahl HG, Microbiol. Biotechnol., 2(2), 186L20 (2009)
  21. Liu XF, Song L, Li L, Li SY, Yao KD, J. Appl. Polym. Sci., 103(6), 3521 (2007)
  22. Vakili M, Deng SB, Cagnetta G, Wang W, Meng PP, Liu DC, Yu G, Sep. Purif. Technol., 224, 373 (2019)
  23. Ngah WS, Teong LC, Hanafiah MAKM, Carbohydr. Polym., 83(4), 1446 (2011)
  24. Yang DX, Li LF, Chen BL, Shi SX, Nie J, Ma GP, Polymer, 163, 74 (2019)
  25. Zhang L, Zeng Y, Cheng Z, J. Mol. Liq., 214, 175 (2016)
  26. Kyzas GZ, Lazaridis NK, J. Colloid Interface Sci., 331(1), 32 (2009)
  27. Lim SH, Hudson SM, Carbohydr. Polym., 56(2), 227 (2004)
  28. Bhuiyan MAR, Hossain MA, Zakaria M, Islam MN, Uddin MZ, J. Polym. Environ., 25(2), 334 (2017)
  29. Srisuk S, Srikulkit K, J. Met. Mater. Miner., 18(2), 41 (2008)
  30. Ali SW, Joshi M, Rajendran S, AATCC Rev., 11(5), 49 (2011)
  31. Gomes AP, Mano JF, Queiroz JA, Gouveia IC, J. Polym. Environ., 20(4), 1084 (2012)
  32. Shirvan AR, Nejad NH, Bashari A, Fibers Polym., 15(9), 1908 (2014)
  33. Pan H, Wang W, Pan Y, Zeng W, Zhan J, Song L, Hu Y, Liew KM, Cellulose, 22(1), 911 (2015)
  34. Fang F, Zhang X, Meng Y, Gu Z, Bao C, Ding X, Li S, Chen X, Tian X, Surf. Coat. Technol., 262, 9 (2015)
  35. Lv Z Hu YT, Guan JP, Tang RC, Chen GQ, Mater. Lett., 241, 136 (2019)
  36. Ren J, Li M, Yuan R, Pang A, Lu Z, Ge L, Colloids Surf. A: Physicochem. Eng. Asp., 586 (2020)
  37. Saini S, Gupta A, Singh N, Sheikh J, J. Ind. Eng. Chem., 82, 138 (2020)
  38. Kundu CK, Wang W, Zhou S, Wang X, Sheng H, Pan Y, Song L, Hu Y, Carbohydr. Polym., 166, 131 (2017)
  39. Tian MW, Hu XL, Qu LJ, Du MZ, Zhu SF, Sun YN, Han GT, Appl. Surf. Sci., 377, 141 (2016)
  40. Tian M, Hu X, Qu L, Zhu S, Sun Y, Han G, Carbon N. Y., 96, 1166 (2016)
  41. Gadkari RR, Suwalka S, Yogi MR, Ali W, Das A, Alagirusamy R, Carbohydr. Polym., 226 (2019)
  42. Qi L, Xu Z, Jiang X, Hu C, Zou X, Carbohydr. Res., 339(16), 2693 (2004)
  43. Chen H, Xing X, Tan H, Jia Y, Zhou T, Chen Y, Ling Z, Hu X, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 70, 287 (2017)
  44. Doyle AA, Kramer T, Kavanagh K, Stephens JC, Results Chem., 1, 100013 (2019)
  45. Chang ST, Chen PF, Chang SC, J. Ethnopharmacol., 77(1), 123 (2001)
  46. Rieger KA, Schiffman JD, Carbohydr. Polym., 113, 561 (2014)
  47. Kenawy E, Omer AM, Tamer TM, Elmeligy MA, Eldin MSM, Int. J. Biol. Macromol., 139, 440 (2019)
  48. Chen H, Hu X, Chen E, Wu S, McClements DJ, Liu S, Li B, Li Y, Food Hydrocolloids, 61, 662 (2016)
  49. Rieger KA, Eagan NM, Schiffman JD, J. Appl. Polym. Sci, 132(13) (2015)
  50. Lei L, He Z, Chen H, McClements DJ, Li B, Li Y, RSC Adv., 5(121), 100114 (2015)
  51. Tsaneva D, Nikolova M, Prokopov T, Petkova N, Stoyanova A, Denev P, J. Pharm. Sci. Res., 9(9), 1609 (2017)
  52. Khalil TE, Elhusseiny AF, El-dissouky A, Ibrahim NM, React. Funct. Polym., 146, 104407 (2020)
  53. Getnet M, Chavan R, Int. J. Sci. Basic Appl. Res., 22(2), 232 (2015)
  54. Dave J, Kumar R, Srivastava HC, J. Appl. Polym. Sci., 33(2), 455 (1987)
  55. Palme A, Peterson A, de la Motte H, Theliander H, Brelid H, Text. Cloth. Sustain., 3(1) (2017)
  56. Wang Q, Hauser PJ, Cellulose, 16(6), 1123 (2009)
  57. Bhattacharjee S, J. Control. Release, 235, 337 (2016)
  58. Li H, Chen Q, Zhao J, Urmila K, Sci. Rep., 5, 1 (2015)
  59. Nath J, Chowdhury A, Ali I, Dolui SK, J. Appl. Polym. Sci., 136(22), 1 (2019)
  60. Ngah WSW, Ariff NFM, Hashim A, Hanafiah MAKM, Clean Soil Air Water, 38(4), 394 (2010)
  61. Shamsudin MS, Shahadat M, J. Water Process Eng., 29, 100764 (2019)
  62. Gadkari R, Kumar B, Ali W, Das A, Alagirusamy R, Indian J. Fibre Text. Res., 45(1), 75 (2020)
  63. Sasikala L, Rathinamoorthy R, Durai B, Indian J. Fibre Text. Res., 44(2), 148 (2019)
  64. Thilagavathi G, Muthukumar N, Neelakrishnan S, Egappan RS, J. Ind. Text., 48(10), 1566 (2019)
  65. Fotovvati B, Namdari N, Dehghanghadikolaei A, J. Manuf. Mater. Process., 3(1), 28 (2019)
  66. Moiz A, Padhye R, Wang X, Coatings, 8(3), 104 (2018)
  67. Chung YC, Wang HL, Chen YM, Li SL, Bioresour. Technol., 83(3), 179 (2003)
  68. No HK, Park NY, Lee SH, Meyers SP, Int. J. Food Microbiol., 74(1-2), 65 (2002)
  69. Meng X, Xing R, Liu S, Yu H, Li K, Qin Y, Li P, Int. J. Biol. Macromol., 50(4), 918 (2012)
  70. Marakova N, Humpolicek P, Kasparkova V, Capakova Z, Martinkova L, Bober P, Trchova M, Stejskal J, Appl. Surf. Sci., 396, 169 (2017)
  71. Shukla SK, Mishra AK, Arotiba OA, Mamba BB, Int. J. Biol. Macromol., 59, 46 (2013)
  72. Wu Y, Pang H, Liu Y, Wang X, Yu S, Fu D, Chen J, Wang X, Environ. Pollut., 246, 608 (2019)
  73. Nabi SA, Shahadat M, Bushra R, Shalla AH, Chem. Eng. J., 175, 8 (2011)
  74. Yu K, Ho J, McCandlish E, Buckley B, Patel R, Li Z, Shapley NC, Colloids Surf. A: Physicochem. Eng. Asp., 425, 31 (2013)
  75. Olivera S, Muralidhara HB, Venkatesh K, Guna VK, Gopalakrishna K, Kumar YK, Carbohydr. Polym., 153, 600 (2016)
  76. Ugur SS, Sariisik M, Aktas AH, Ucar MC, Erden E, Nanoscale Res. Lett., 5(7), 1204 (2010)
  77. Fahmy HM, Aly AA, Abou-Okeil A, Int. J. Biol. Macromol., 114, 929 (2018)
  78. Donelli I, Freddi G, Nierstrasz VA, Taddei P, Polym. Degrad. Stabil., 95(9), 1542 (2010)
  79. Vigneswaran C, Anbumani N, J. Text. Inst., 102(2), 140 (2011)
  80. Debnath S, Madhusoothanan M, J. Ind. Text., 41(4), 292 (2012)
  81. Ali SW, Joshi M, Rajendran S, Adv. Sci. Lett., 3(4), 452 (2010)