Fabrication of AuNPs into alginate biopolymer and functionalized by thiourea as a film shape probe for palladium(II) sensing

Nahid Pourreza; Parichehr Abasipanah; Matineh Ghomi

Journal of Industrial and Engineering Chemistry, Vol.100, 194-203, August, 2021

DOI10.1016/j.jiec.2021.05.023 Export Citation

Fabrication of AuNPs into alginate biopolymer and functionalized by thiourea as a film shape probe for palladium(II) sensing

Nahid Pourreza^†, Parichehr Abasipanah, and Matineh Ghomi

Department of Chemistry, Faculty of Science, Shahid Chamran University of Ahvaz, Ahvaz, Iran

E-mail:

A simple process was developed for the fabrication of alginate biopolymer film embedded by thiourea- functionalized AuNPs (thiourea/AuNPs) for palladium(II) detection. A mixture of sodium alginate and HAuCl4 was prepared as the main matrix and the AuNPs were in situ synthesized in alkali media provided by borax. The AuNPs entrapped in the alginate network were functionalized by thiourea and fabricated as a transparent film. The characteristics of thiourea/AuNPs alginate biopolymer film were investigated by Transmission electron microscopy (TEM), Energy dispersive X-ray analysis (EDX) and UV.vis spectrophotometry. The UV.vis absorption spectrum showed the maximum wavelength of thiourea/ AuNPs was at 530 nm. The effect of various parameters such as pH and thiourea concentration on the sensing of palladium(II) ions was investigated. The prepared alginate biopolymer film showed good stability over the time. The calibration graph was linear in the range of 0.05-2.10 μg mL-1 with a detection limit of 0.038 μg mL-1. The relative standard deviation (n = 10) for 0.6 and 1.2 μg mL-1 of palladium(II) was 4.6% and 3.5%, respectively. The sensing system was successfully applied for the determination of palladium in walnut leaves, wastewater, dental amalgam, and ceramic capacitor samples.

Keywords:Alginate;Biopolymer film;Palladium(II) ions;Thiourea/AuNPs;Sensing;Colorimetric

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[2] Garcia-Astrain C, Averous L, Carbohydr. Polym., 190, 271 (2018)

[3] Yang X, Lu Z, Wu H, Li W, Zheng L, Zhao J, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 83, 195 (2018)

[4] Noh HL, Park YK, Oh BM, Zheng J, Kim SH, Lee W, Kim JH, Sens. Actuators B-Chem., 301, 127079 (2019)

[5] Xue L, Wang W, Guo Y, Liu G, Wan P, Sens. Actuators B-Chem., 244, 47 (2017)

[6] Saleh SM, Alminderej FM, Ali R, Abdallah OI, Spectrochim. Acta A: Mol. Biomol. Spectrosc., 117971 (2019).

[7] Saraji M, Tarami M, Mehrafza N, Microchem. J., 150, 104171 (2019)

[8] Cheng H, Jin W, Huang X, Liu X, Wang F, Guo X, Wu Y, Ying Y, Wen Y, Yang H, Nanotechnology, 31, 015505 (2019)

[9] Mane SS, Chatterjee S, Bifunctionality of Carbon Nanotubes, The Electrochemical Society, p.2110 2019.

[10] Li Q, Guan Y, Zhang Y, Sens. Actuators B-Chem., 272, 243 (2018)

[11] Ghosh T, Katiyar V, Cellulose-Based Superabsorbent Hydrogels, pp.1061 (2019).

[12] Buchberger A, Peterka S, Coclite AM, Bergmann A, Sensors, 19, 999 (2019)

[13] Hu J, Hiwatashi K, Kurokawa T, Liang SM, Wu ZL, Gong JP, Macromolecules, 44(19), 7775 (2011)

[14] Teramoto H, Kameda T, Tamada Y, Biosci. Biotechnol. Biochem., 0811051141 (2008).

[15] Tokarev I, Minko S, Soft Matter, 5, 511 (2009)

[16] Chen Y, Zhang M, Han Y, Wei J, RSC Adv., 6, 8380 (2016)

[17] Merget R, Rosner G, Sci. Total Environ., 270, 165 (2001)

[18] Ravindra K, Bencs L, Van Grieken R, Sci. Total Environ., 318, 1 (2004)

[19] Wang K, Lai G, Li Z, Liu M, Shen Y, Wang C, Tetrahedron, 71, 7874 (2015)

[20] Kielhorn J, Melber C, Keller D, Mangelsdorf I, Int. J. Hyg. Environ. Health, 205, 417 (2002)

[21] Liu TZ, Lee SD, Bhatnagar RS, Toxicol. Lett., 4, 469 (1979)

[22] Xiang K, Liu Y, Li C, Tian B, Zhang J, RSC Adv., 5, 52516 (2015)

[23] Luo W, Liu W, J. Mater. Chem. B, 4, 3911 (2016)

[24] Clem RG, Huffman E, Analyt. Chem., 37, 86 (1965)

[25] Kokya TA, Farhadi K, J. Hazard. Mater., 169(1-3), 726 (2009)

[26] Mohammadi SZ, Afzali D, Taher MA, Baghelani YM, Microchim. Acta, 168, 123 (2010)

[27] Azmi SNH, Iqbal B, Al Ruqishi BHK, Al Sayabi SAM, Al Quraini NMK, Rahman N, J. Assoc. Arab Univ. Basic Appl. Sci., 19, 29 (2016)

[28] Shokrollahi A, Ramdar K, J. Taibah Univ. Sci., 11, 782 (2017)

[29] dos Santos Souza EJ, do Amaral CDB, Nagata N, Grassi MT, Microchem. J., 152, 104309 (2020)

[30] ALOthman ZA, Habila MA, Yilmaz E, Alabdullkarem EA, Soylak M, Measurement, 153, 107394 (2020)

[31] Pourreza N, Ghomi M, Talanta, 179, 92 (2018)

[32] Zhao X, Xia Y, Li Q, Ma X, Quan F, Geng C, Han Z, Colloids Surf. A: Physicochem. Eng. Asp., 444, 180 (2014)

[33] Zhao X, Li Z, Deng Y, Zhao Z, Li X, Xia Y, Materials, 10, 557 (2017)

[34] Gao X, Liu J, Li M, Guo C, Long H, Zhang Y, Xin L, Chem. Eng. J., 385, 123897 (2020)

[35] Chai F, Wang C, Wang T, Ma Z, Su Z, Nanotechnology, 21, 025501 (2009)

[36] Chen C, Zhao D, Sun J, Yang X, Analyst, 141, 2581 (2016)

[37] Arrigo R, Schuster ME, Xie Z, Yi Y, Wowsnick G, Sun LL, Hermann KE, Friedrich M, Kast P, Havecker M, ACS Catal., 5, 2740 (2015)

[38] Gao X, Zhang Y, Zhao Y, Carbohydr. Polym., 159, 108 (2017)

[39] Farrokhpour H, Gerami M, J. Mol. Liq., 116090 (2021).

[40] Cao J, Xu G, Xie Y, Tao M, Zhang W, RSC Adv., 6, 58088 (2016)

[41] Khairul WM, Wahab FFA, Soh SKC, Shamsuddin M, Daud AI, Chem. Phys. Lett., 756, 137841 (2020)

[42] Zhao Y, Fu Q, Cui X, Chi H, Lu Y, Liu X, Yu M, Fei Q, Geng G, Shan H, Analyt. Methods, 13, 1069 (2021)

[43] Maaz K, Karim S, Mashiatullah A, Liu J, Hou M, Sun Y, Duan J, Yao H, Mo D, Chen Y, Phys. B: Condens. Matter, 404, 3947 (2009)

[44] Ghaedi M, Shokrollahi A, Niknam K, Niknam E, Najibi A, Soylak M, J. Hazard. Mater., 168(2-3), 1022 (2009)