화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.101, 144-152, September, 2021
DOI10.1016/j.jiec.2021.06.019  Export Citation
Improved lithium storage performance of CeO2-decorated SrLi2Ti6O14 material as an anode for Li-ion battery
Ying Li1, Hong-Yan Liu1, 2, Ling-Na Shi1, 2, Yan-Rong Zhu1, 2, and Ting-Feng Yi1, 2, †
  • 1School of Materials Science and Engineering, Northeastern University, Shenyang 110819, PR China
  • 2Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, Qinhuangdao 066004, PR China
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In this work, the CeO2-decorated SrLi2Ti6O14 anode was successfully prepared through a solid-state process. The space-charge effect induced by the internal adsorption of ions on the CeO2 surface can easily result in a formation of an excellent conductive interfacial layer between CeO2 and SrLi2Ti6O14. The good electrical contact between CeO2 and SrLi2Ti6O14 offers more active sites for the electrolyte storage and redox reaction, and promotes the intercalation/deintercalation of lithium ions, and thus improves the rate performance and cycle stability. Due to its unique structure and composition, the CeO2-decorated SrLi2Ti6O14 composites exhibit high reversible capacities, good cycle performance and outstanding rate performance. Especially, the CeO2 (5 wt%)-decorated SrLi2Ti6O14 anode shows the most excellent electrochemical performance, which delivers a large charge capacity of 121.3 mAh g-1 and a capacity retention of 94.48% after 100 cycles at 0.5 A g-1. However, the corresponding charge capacity and capacity retention of pristine SrLi2Ti6O14 are 100.5 mAh g-1 and 86.77%, respectively. The CeO2(5 wt%)-decorated SrLi2Ti6O14 with enhanced rate capacity, cycle stability and structural stability is a potential electrode material candidate for Li-ion battery.
Keywords:SrLi2Ti6O14;CeO2;Anode material;Li-ion battery
  1. Yu P, Tang W, Wu FF, Zhang C, Luo HY, Liu H, Wang ZG, Rare Met., 39, 1019 (2020)
  2. Pavithra NS, Patil SB, Kumar SRK, Alharthi FA, Nagaraju G, SN Appl. Sci., 1, 1123 (2019)
  3. Shashank M, Alharthi FA, Alsalme A, Al-Zaqri N, Nagaraju G, J. Mater. Sci., 31, 14279 (2020)
  4. Udayabhanu, Pavitra V, Shivanna M, Alharthi FA, Praveen BM, Ravikiran YT, Byrappa K, Nagaraju G, Int. J. Energy Res. (2021).
  5. Jeon JW, Biswas MC, Patton CL, Wujcik EK, J. Ind. Eng. Chem., 84, 72 (2020)
  6. Borghols WJH, Wagemaker M, Lafont U, Kelder EM, Mulder FM, J. Am. Chem. Soc., 131(49), 17786 (2009)
  7. Li KQ, Zhang Y, Sun YN, Xu YL, Zhang H, Ye P, Zheng MD, Zhou N, Wang D, Appl. Surf. Sci., 459, 572 (2018)
  8. Song XY, Zhang YH, Sun PP, Gao J, Shi FN, Chem. Eur. J., 26, 5654 (2020)
  9. Hu J, Zheng J, Pan F, Acta Phys.-Chim. Sin., 35, 361 (2019)
  10. Liu K, Liu Y, Zhu H, Dong X, Wang Y, Wang C, Xia Y, Acta Phys. -Chim. Sin., 36, 191203 (2020)
  11. Fan SS, Zhong H, Yu HT, Lou M, Xie Y, Zhu YR, Sci. China-Mater., 60, 427 (2017)
  12. Yi TF, Xie Y, Zhu YR, Zhu RS, Shen HY, J. Power Sources, 222, 448 (2013)
  13. Qin W, Liu H, An J, Wen X, J. Power Sources, 479 (2020)
  14. Sun X, Radovanovic PV, Cui B, New J. Chem., 39, 38 (2015)
  15. Liu JH, Li YA, Wang XQ, Gao Y, Wu NN, Wu BR, J. Alloy. Compd., 581, 236 (2013)
  16. Rambabu A, Senthilkumar B, Dayamani A, Krupanidhi SB, Barpanda P, Electrochim. Acta, 269, 212 (2018)
  17. Peng N, Zhu HJ, Cheng X, Yu HX, Liu TT, Zheng RT, Zhang JD, Shui M, Shu J, Electrochim. Acta, 265, 437 (2018)
  18. Qian SS, Yu HX, Yan L, Li P, Lan H, Zhu HJ, Long NB, Shui M, Shu J, J. Power Sources, 343, 329 (2017)
  19. Zhang YY, Qian SS, Zhu HJ, Cheng X, Ye WQ, Yu HX, Yan L, Shui M, Shu J, Ceram. Int., 43, 12357 (2017)
  20. Kang Y, Zhang YH, Sun PP, Huang PB, Yu X, Shi Q, Tian B, Gao J, Shi FN, Solid State Ion., 350 (2020)
  21. Kang Y, Zhang YH, Shi Q, Shi HW, Xue DF, Shi FN, J. Colloid Interface Sci., 585, 705 (2021)
  22. Zhang S, Zhang M, Qu Y, Acta Phys. -Chim. Sin., 36, 191105 (2020)
  23. Prathap C, Kumar VVR, Rao MV, Nagaiah P, Rao SRK, Raju BD, J. Ind. Eng. Chem., 79, 97 (2019)
  24. Yuan W, Zhang HZ, Liu Q, Li GR, Gao XP, Electrochim. Acta, 135, 199 (2014)
  25. Hua C, Fang X, Yang Z, Gao Y, Wang Z, Chen L, Electrochem. Commun., 25, 66 (2012)
  26. Wang K, Zhang FZ, Zhu GJ, Zhang H, Zhao YY, She L, Yang JP, A.C.S. Appl. Mater. Interfaces, 11, 33082 (2019)
  27. Dayamani A, Shinde GS, Chaupatnaik A, Rao RP, Adams S, Barpanda P, J. Power Sources, 385, 122 (2018)
  28. Gong QH, Gao TT, Huang H, Wang RX, Cao P, Zhou GW, Inorg. Chem. Front., 5, 3197 (2018)
  29. Dong SD, Zhou Y, Hai CX, Zeng JB, Sun YX, Shen Y, Li X, Ren XF, Qi GC, Zhang XX, Ma LX, Ceram. Int., 45, 144 (2019)
  30. Han ZS, Kong FJ, He XL, Tao S, Jiang XF, Qian B, J. Phys. Chem. Solids, 134, 187 (2019)
  31. Hu GR, Xue ZC, Luo ZY, Peng ZD, Cao YB, Wang WG, Zeng YX, Huang Y, Tao Y, Li TF, Zhang ZY, Du K, Ceram. Int., 45, 10633 (2019)
  32. Miller DJ, Biesinger MC, McIntyre NS, Surf. Interface Anal., 33, 299 (2002)
  33. Deng XQ, Li WR, Zhu MH, Xiong DP, He M, Solid State Ion., 364 (2021)
  34. Qu ZT, Liu ST, Zhang P, Wang R, Wang HW, He BB, Gong YS, Jin J, Li S, Solid State Ion., 365 (2021)
  35. Ogunniran KO, Murugados G, Thangamuthu R, Nishanthi ST, J. Alloy. Compd., 786, 873 (2019)
  36. Wu JH, Han C, Wu H, Liu H, Zhang Y, Lu C, Ionics, 25, 3031 (2019)
  37. Yi T, Shi L, Han X, Wang F, Zhu Y, Xie Y, Energy Environ. Mater. (2020).
  38. Song XY, Zhang YH, Sun PP, Gao J, Shi FN, Chem. Eur. J., 26, 5654 (2020)
  39. Li H, Shen L, Ding B, Pang G, Dou H, Zhang X, Nano Energy, 13, 18 (2015)
  40. Pelegov DV, Koshkina AA, Pryakhina VI, Gorshkov VS, J. Electrochem. Soc., 166(3), A5019 (2018)
  41. Shi Y, Yu R, Yang D, Liu Y, Qu J, Liu B, Yu ZZ, Electrochim. Acta, 321 (2019)
  42. Zhong W, Tao M, Tang W, Gao W, Yang T, Zhang Y, Zhan R, Bao SJ, Xu M, Chem. Eng. J., 378 (2019)
  43. Li Z, Huang Y, Jiang Y, Wang Z, Lu B, Zhou J, Xie M, ChemElectroChem, 7, 2258 (2020)
  44. Song T, Ye S, Liu H, Wang YG, J. Alloy. Compd., 767, 820 (2018)
  45. Bai JD, Zhang YH, Shi H, Shi Q, Shi FN, J. Solid State Chem., 298 (2021)
  46. Lin XT, Li P, Wang PF, Yu HX, Qian SS, Shui M, Zheng X, Long NB, Shu J, Electrochim. Acta, 180, 831 (2015)
  47. Ding HL, Yu HT, Guo CF, Xie Y, Yi TF, Electrochim. Acta, 329, 10 (2020)
  48. Dambournet D, Belharouak I, Ma JW, Amine K, J. Power Sources, 196(5), 2871 (2011)
  49. Sun PP, Zhang YH, Mu J, Tian B, Shi FN, Inorg. Chem. Commun., 125 (2021)
  50. Alharthi FA, Alsaiari MA, Jalalah MS, Shashank M, Shashikanth, Alghamdi AA, Algethami JS, Ganganagappa N, Ceram. Int., 47, 10291 (2021)
  51. Zhu HJ, Liu TT, Peng L, Yao WT, Kang FY, Shu J, Yang C, Nano Energy, 82 (2021)
  52. Liu TT, Peng N, Zhang XK, Zheng RT, Xia MT, Yu HX, Shui M, Xie Y, Shu J, Nano Energy, 79 (2021)
  53. Yu HX, Deng CC, Yan HH, Xia MT, Zhang XK, Wang ZB, Shu J, Nano-Micro Lett., 13, 41 (2021)
  54. Jacob MM, Rajendran S, Gangadharan R, Michael MS, Prabaharan SR, Solid State Ion., 86-88, 595 (1996)