화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.101, 227-236, September, 2021
DOI10.1016/j.jiec.2021.06.009  Export Citation
Akebia trifoliate koiaz peels extract as environmentally benign corrosion inhibitor for mild steel in HCl solutions: Integrated experimental and theoretical investigations
Mengqin Zhang1, 2, Lei Guo1, 3, †, Mengyue Zhu4, Kai Wang1, Renhui Zhang4, Zhongyi He4, †, Yuanhua Lin3, Senlin Leng1, Valentine Chikaodili Anadebe5, 6, and Xingwen Zheng7
  • 1School of Material and Chemical Engineering, Tongren University, Tongren 554300, China
  • 2Guizhou Provincial Key Laboratory for Biodiversity Conservation and Utilization in the Fanjing Mountain Region, Tongren University, Guizhou 554300, China
  • 3School of Oil and Natural Gas Engineering, Southwest Petroleum University, Chengdu 610500, China
  • 4School of Materials Science and Engineering, East China Jiaotong University, Nanchang 330013, China
  • 5Department of Chemical Engineering, Federal University Ndufu Alike, Ebonyi State, Nigeria
  • 6CSIR-Central Electrochemical Research Institute, Karaikudi, 630003, India
  • 7Key Laboratory of Material Corrosion and Protection of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
E-mail:,
In this account, pectin components were obtained from akebia trifoliate koiaz peels with the acid extraction technology. The chemical constituent of the akebia trifoliate koiaz peels extract (ATKPE) was analyzed and its anti-corrosion performance for mild steel in HCl medium was investigated by electrochemical methods, surface analysis and theoretical calculations. Experimental results show that ATKPE exhibits excellent corrosion inhibition characteristic, and its inhibition efficiency can be as high as 90% when the concentration of ATKPE is 800 mg/L. Electrochemical measurements show that ATKPE is a mixed-type corrosion inhibitor consisting with Langmuir adsorption model. In addition, SEM, AFM and contact angle observations suggests that the ATKPE may attach firmly to the metal surface by forming a barrier film. XPS and ATR-FTIR results further verify the bonding interaction between the functional groups and steel substrate. Meanwhile, quantum chemical calculations and molecular dynamics (MD) simulations were performed to reveal the inhibition mechanism at molecular/atomic level. In brief, our findings demonstrate a novel environmentally benign, efficient corrosion inhibitor for steel protection in acidic media.
Keywords:Akebia trifoliate koiaz peels extract;Corrosion inhibitor;Mild steel;Electrochemistry;Molecular simulation
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